Oil from tyre pyrolysis as a plasticizer in rubber compounds

Cezary Dębek

doi:10.14314/polimery.2019.7.10

Published : 2021-01-12

Vol. 64 No. 7-8 (2019)

Oil from tyre pyrolysis as a plasticizer in rubber compounds

Cezary Dębek

DOI: https://doi.org/10.14314/polimery.2019.7.10

Abstract

The paper presents the results of research on the possibility of using as plasticizers of rubber compounds the heavy fractions of pyrolytic oil obtained in the industrial process of pyrolysis of car tyres. The content of carcinogenic polycyclic aromatic hydrocarbons (PAHs) in the obtained pyrolytic plasticizers was determined. Compounds and vulcanizates of styrene-butadiene rubber (SBR) containing the above plasticizers as well as commercial petroleum derivatives’ plasticizers were prepared for comparative purposes. The basic properties of compounds and vulcanizates containing pyrolytic plasticizers were investigated. The research showed that one fraction of pyrolysis oil meet the requirements of the permitted content of PAHs. SBR blends and vulcanizates have similar properties as in the case of commercial plasticizers.

Keywords

tyre pyrolysis ; pyrolytic oil ; plasticizer ; rubber compound ; vulcanizate ; rubber piroliza opon ; olej popirolityczny ; plastyfikator ; mieszanka kauczukowa ; wulkanizat ; guma

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Dębek, C. (2021). Oil from tyre pyrolysis as a plasticizer in rubber compounds. Polimery, 64(7-8), 530-537. https://doi.org/10.14314/polimery.2019.7.10

References

Williams P.T.: Waste Management 2013, 33, 1714.
Crossref

[2] Martinez J.D., Puy N., Murillo R. et al.: Renewable and Sustainable Energy Review 2013, 23, 179.
Crossref

[3] Dębek C., Walendziewski J.: Fuel 2015, 159, 659.
Crossref

[4] Dębek C.: Materials 2019, 12 (6), 880.
Crossref

[5] Ostaszewska U., Dębek C., Magryta J.: “Pyrolysis of used rubber products as a source of carbon secondary raw material” (in Polish), Institute for Engineering of Polymer Materials and Dyes, Toruń 2014, pp. 7–29.

[6] Dębek C., Magryta J., Sobczak M. et al.: Przemysł Chemiczny 2010, 89, 242.

[7] Dębek C.: Elastomery 2018, 22, 281.

[8] Dębek C., Stępkowski R., Magryta J. et al.: Elastomery 2009, 13, 24.

[9] Magryta J., Dębek C., Stępkowski R. et al.: Elastomery 2009, 13, 21.

[10] Roy C., Chaala A., Darmstadt H.: Journal of Analytical and Applied Pyrolysis 1999, 51, 201.
Crossref

[11] Directive 2000/76/EC of the European Parliament and of the Council of 4 December 2000 on the incineration of waste, Official Journal L 332, 28/12/2000, pp. 0091–0111.

[12] Quek A., Balasubramanian R.: Journal of Analytical and Applied Pyrolysis 2013, 101, 1.
Crossref

[13] Aydın H., Ilkılıç C.: Fuel 2012, 102, 605.
Crossref

[14] PN-C-96024:2011 “Petroleum products – Fuel oils”.

[15] Directive 2005/69/EC of the European Parliament and of the Council of 16 November 2005 amending for the twenty-seventh time Council Directive 76/769/EEC of 27 July 1976.

[16] Parasiewicz W., Pyskło L.: Elastomery 2005, 9, 25.

[17] Ptak S.: Nafta-Gaz 2017, 73, 675.
Crossref

[18] Ptak S., Antosz A., Jakóbiec J.: Nafta-Gaz 2018, 74, 49.
Crossref

[19] Dębek C., Stępkowski R.: “Ingredients of rubber compounds (vulcanizates), vulcanization, unpublished training materials” (in Polish), Department of Elastomers and Rubber Technology in Piastów Institute of Engineering of Polymer Materials and Dyes, Toruń 21.07.2010.

[20] Stępkowska A., Parys T., Kleps T.: Elastomery 2013, 17, 19.

[21] Łuksa A., Sobczak M., Goś M.: Przemysł Chemiczny 2008, 87, 715.

[22] ASTM D3191-02 “Standard Test Methods for Carbon Black in SBR (Styrene-Butadiene-Rubber)-Recipe and Evaluation Procedures”.

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