Green thermoplastic poly(ether-urethane)s – synthesis, chemical structure and selected properties investigation

Paulina Kasprzyk; Kamila Błażek; Paulina Parcheta; Janusz Datta

doi:10.14314/polimery.2020.10.2

Published : 2020-12-16

Vol. 65 No. 10 (2020)

Green thermoplastic poly(ether-urethane)s – synthesis, chemical structure and selected properties investigation

Paulina Kasprzyk Kamila Błażek Paulina Parcheta Janusz Datta

DOI: https://doi.org/10.14314/polimery.2020.10.2

Abstract

This work aimed to characterize the effect of the monomers chemical structure on the selected properties of the green thermoplastic poly(ether-urethane)s. During synthesis two types of polyether biopolyols, 4,4′-diphenylmethane diisocyanate and bio-based 1,3-propanediol were employed. Materials were synthesized with the use of two step method and two different prepolymers, which were mixed together in equimolar quantities. Obtained materials were characterized by spectroscopic method, size exclusion chromatography, thermal, static mechanical and melt flow index tests. It was confirmed that the prepolymers mixture has an effect on the thermal stability and selected properties of synthesized green thermoplastic poly(ether-urethane)s.

Keywords

thermoplastic polyurethanes ; green poly(ether-urethane)s ; bio-based polyol ; chemical structure ; analysis ; thermal analysis ; melt flow index termoplastyczne poliuretany ; zielone poli(etero-uretany) ; biopoliole ; analiza struktury chemicznej ; analiza termiczna ; wskaźnik szybkości płynięcia

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Kasprzyk, P., Błażek, K., Parcheta, P., & Datta, J. (2020). Green thermoplastic poly(ether-urethane)s – synthesis, chemical structure and selected properties investigation. Polimery, 65(10), 672—680. https://doi.org/10.14314/polimery.2020.10.2

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Paulina Kasprzyk

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80233 Gdańsk, Poland

Kamila Błażek

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80233 Gdańsk, Poland

Paulina Parcheta

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80233 Gdańsk, Poland

Janusz Datta janusz.datta@pg.edu.pl

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80233 Gdańsk, Poland