Epoxy resin crosslinked with conventional and deep eutectic ionic liquids

H. Maka; T. Spychaj

Published : 2012-06-30

Vol. 57 No. 6 (2012)

Epoxy resin crosslinked with conventional and deep eutectic ionic liquids

H. Maka T. Spychaj

Abstract

Molecular ionic liquid, i.e. 1-ethyl-3-methylimidazolium chloride ([EMIM]Cl) and eutectic mixture of imidazole with choline chloride (IM + ChCl) have been used as epoxy resin hardeners. An influence of [EMIM]Cl and IM + ChCl content on pot life of epoxy compositions and runs of crosslinking process has been evaluated using DSC and ARES rheometry techniques. Epoxy compositions with [EMIM]Cl showed latent properties (pot life up to 50 days) while the systems with IM + ChCl gelled after few days. Comparative measurement of thermomechanical (Tg, tan d) and mechanical properties (tensile, flexural and shear strength on aluminum substrates) as well as thermal decomposition of epoxy composites have been performed. Composite epoxy materials crosslinked with [EMIM]Cl exhibited more elastic properties (lower Tg and higher tan d values) and generally better mechanical features than those hardened with imidazole + choline chloride eutectic mixture.

Keywords

żywica epoksydowa ; ciecz jonowa ; mieszanina eutektyczna ; analiza termiczna ; sieciowanie ; kompozycje epoksydowe ; kompozyty epoksydowe epoxy resin ; ionic liquid ; eutectic mixture ; thermal analysis ; curing characteristics ; epoxy compositions

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Maka, H., & Spychaj, T. (2012). Epoxy resin crosslinked with conventional and deep eutectic ionic liquids. Polimery, 57(6), 456-462. Retrieved from http://ichp.vot.pl/index.php/p/article/view/843

References

Czub P., Bończa-Tomaszewski Z., Penczek P., Pielichowski J.: „Chemistry and technology of epoxy resins”, WNT,Warsaw 2002.

2. Barton J. M., Hamerton I., Howlin B. J., Jones J. R., Lin S.: Polym. Bull. 1994, 33, 347.

3. Brown J., Hammerton I., Howlin B. J.: J. Appl. Polym. Sci. 2000, 75, 201.

4. Pilawka R., Spychaj T., Leistner A.: Polimery 2008, 53, 526.

5. Kubisa P.: Prog. Polym. Sci. 2009, 34, 1333.

6. Weyershausen B., Lehmann K.: Green Chem. 2005, 7, 15.

7. Wan S., Zhang X., Wang H.: Polym. Adv. Technol. 2009, 20, 857.

8. Wilpiszewska K., Spychaj T.: Carbohydr. Polym. 2011, 86, 424.

9. Tan S. S. Y., MacFarlane D. R.: Top. Curr. Chem. 2010, 290, 311.

10. Zhu S., Wu Y., Chen Q., Yu Z., Wang C., Jin S., Ding Y., Wu G.: Green Chem. 2006, 8, 325.

11. Zdanowicz M., Spychaj T.: Polimery 2011, 56, 861.

12. Olivier-Bourbigou Helenc H., Magna L., Morvan D.: Appl. Catal. A: General 2010, 373, 1.

13. Kowalczyk K., Spychaj T.: Polimery 2003, 48, 833.

14. Rahmathullah A. M., Jeyarajasingam A., Merritt B., Van- Landingham M., McKnight S. H., Palmese G. R.: Macromolecules 2009, 42, 3219.

15. Soares B. G., Livi S., Duchert-Rumeau J., Gerard J. F.: Macromol. Mater. Eng. 2011, 296 (9), 826.

16. M¹ka H., Spychaj T., Pilawka R.: Ind. Eng. Chem. Res.: sent to redaction/accepted doi.org/10.1021/ie202321j

17. Abbott A. P., Capper G., Davies B. L., Rasheed R. K.: Chem. Commun. 2003, 70.

18. Iišova V.: J. Appl. Polym. Sci. 1987, 34, 2547.

19. Ham J. S., Kim S. H., Shin Y. J., Lee D. H., Yang M., Min J. H., Shin J. S.: J. Ind. Eng. Chem. 2010, 16, 556.

Google Scholar

Citing articles via

Statistics

Total abstract views : 241

PDF Downloads : 112