Vanadium catalysts for ethylene-norbornene. Copolymerization

Anna Bihun-Kisiel; Wioletta Ochędzan-Siodłak

doi:10.14314/polimery.2020.11.2

Published : 2020-12-17

Vol. 65 No. 11-12 (2020)

Vanadium catalysts for ethylene-norbornene. Copolymerization

Anna Bihun-Kisiel Wioletta Ochędzan-Siodłak

DOI: https://doi.org/10.14314/polimery.2020.11.2

Abstract

Cyclic olefin copolymers (COCs) are a promising group of materials with specific, projectable properties. In this group, copolymers of ethylene and norbornene are of particular interest. A variety of transition metal complexes are used for their synthesis, mostly elements from group 4. This review presents the application of vanadium catalysts with various types of ligands in the synthesis of ethylene-norbornene copolymers. The influence of ligands and reaction conditions on the activity of catalyst and selected properties of copolymers are described in this paper.

Keywords

vanadium catalyst ; copolymerization ; ethylene ; norbornene ; cyclic olefin copolymers katalizator wanadowy ; kopolimeryzacja ; etylen ; norbornen ; kopolimery cyklicznych olefin

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Bihun-Kisiel, A., & Ochędzan-Siodłak, W. (2020). Vanadium catalysts for ethylene-norbornene. Copolymerization. Polimery, 65(11-12), 757-770. https://doi.org/10.14314/polimery.2020.11.2

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Crossref

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Crossref

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Anna Bihun-Kisiel abihun@uni.opole.pl

Affiliation
Opole University, Faculty of Chemistry, Chair of Chemical Technology and Polymer Chemistry, Oleska 48, 45-052 Opole, Poland

Wioletta Ochędzan-Siodłak

Affiliation
Opole University, Faculty of Chemistry, Chair of Chemical Technology and Polymer Chemistry, Oleska 48, 45-052 Opole, Poland