The influence of halloysite on the physicochemical, mechanical and biological properties of polyurethane- -based nanocomposites

Maciej Mrówka; Małgorzata Szymiczek; Tomasz Machoczek; Joanna Lenża; Jakub Matusik; Piotr Sakiewicz; Magdalena Skonieczna

doi:10.14314/polimery.2020.11.5

Published : 2020-12-17

Vol. 65 No. 11-12 (2020)

The influence of halloysite on the physicochemical, mechanical and biological properties of polyurethane- -based nanocomposites

Maciej Mrówka Małgorzata Szymiczek Tomasz Machoczek Joanna Lenża Jakub Matusik Piotr Sakiewicz Magdalena Skonieczna

DOI: https://doi.org/10.14314/polimery.2020.11.5

Abstract

The impact of the addition of the nanofiller – halloysite – on the mechanical, physicochemical and biological properties of a nanocomposite, in which thermoplastic polyurethane fulfilled the role of the matrix was investigated. The nanocomposite was obtained by extrusion in three variants with 1, 2 and 3 wt % halloysite. The nanostructure of the obtained materials was confirmed using Atomic Force Microscopy (AFM). Based on the mechanical tests carried out, it was proven that the obtained nanocomposites were characterized by a tensile modulus greater than the polyurethane constituting the matrix. The density and hardness of the nanocomposites had changed within error limits compared to unmodified polyurethane. Biological tests showed no cytotoxicity of all the tested materials to normal human dermal fibroblasts (NHDF). Degradation tests were carried out in artificial plasma and showed that samples with 2 wt % halloysite addition had the best ratio of tensile strength and elongation at break to elasticity modulus.

Keywords

nanocomposites ; thermoplastic polyurethanes ; halloysite ; mechanical properties ; cytotoxicity ; tests ; degradation nanokompozyty ; termoplastyczne poliuretany ; haloizyt ; właściwości mechaniczne ; badania cytotoksyczne ; degradacja

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Mrówka, M., Szymiczek, M., Machoczek, T., Lenża, J., Matusik, J., Sakiewicz, P., & Skonieczna, M. (2020). The influence of halloysite on the physicochemical, mechanical and biological properties of polyurethane- -based nanocomposites. Polimery, 65(11-12), 784-791. https://doi.org/10.14314/polimery.2020.11.5

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Maciej Mrówka maciej.mrowka@polsl.pl

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Theoretical and Applied Mechanics, Konarskiego 18A, 44–100 Gliwice, Poland

Małgorzata Szymiczek

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Theoretical and Applied Mechanics, Konarskiego 18A, 44–100 Gliwice, Poland

Tomasz Machoczek

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Theoretical and Applied Mechanics, Konarskiego 18A, 44–100 Gliwice, Poland

Joanna Lenża

Affiliation
Krahn Chemie Polska Sp. z o.o., Marcelińska 90, 60–324 Poznań, Poland

Jakub Matusik

Affiliation
AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Department of Mineralogy, Petrography and Geochemistry, Mickiewicza 30, 30-059 Krakow, Poland.

Piotr Sakiewicz

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Engineering Materials and Biomaterials, Konarskiego 18A, 44–100 Gliwice, Poland

Magdalena Skonieczna

Affiliation
Silesian University of Technology, Biotechnology Centre, Krzywoustego 8, 44–100 Gliwice, Poland.