Synthesis of molecularly printed methyl methacrylate-based polymers for the detection of di(2-ethylhexyl) phthalate and dibutyl phthalate

St. Fauziah; Nunuk Hariani Soekamto; Budi Prastawa; Herlina Rasyid; Nur Haedar; Muralia Hustim; Marlina Marlina; Magfirah Sulaiman; Ajuk Sapar

doi:10.14314/polimery.2023.7.7

Published : 2023-10-13

Vol. 68 No. 7-8 (2023)

Synthesis of molecularly printed methyl methacrylate-based polymers for the detection of di(2-ethylhexyl) phthalate and dibutyl phthalate

St. Fauziah https://orcid.org/0000-0002-0599-4011 Nunuk Hariani Soekamto https://orcid.org/0000-0001-8281-1752 Budi Prastawa https://orcid.org/0000-0002-1266-5232 Herlina Rasyid https://orcid.org/0000-0001-9136-9716 Nur Haedar https://orcid.org/0000-0002-6200-298X Muralia Hustim https://orcid.org/0000-0001-8323-1549 Marlina Marlina https://orcid.org/0009-0008-0629-7614 Magfirah Sulaiman https://orcid.org/0009-0009-5156-7844 Ajuk Sapar https://orcid.org/0000-0002-7278-6159

DOI: https://doi.org/10.14314/polimery.2023.7.7

Abstract

Molecularly imprinted polymers (MIP) were obtained by precipitation polymerization for the detection of DEHP and DBP from polymer packaging in drinking water. MIP was obtained by cross-linking DEHP and DBP with methyl methacrylate (MMA) and trimethylolpropane trimethacrylate (TRIM). FTIR, SEM-EDS, UV-Vis and SAA were used to determine properties of polymers (MIP_DEHP, MIP_DBP). The obtained materials were characterized by a mesoporous structure with small, uniform, and porous grains. The surface area and total pore volume of MIP_DEHP were more than twice smaller than MIP_DBP, with a slightly larger pore diameter. Lower C content may indicate the formation of MIP_DEHP and MIP_DBP. The FTIR method confirmed the presence of functional groups –CH, –CO, –C=C and –C=O. The adsorption capacity of MIP_DEHP and MIP_DBP was 0.68 mg/g and 1.06 mg/g, respectively, and was consistent with the Freundlich isothermal adsorption model.

Keywords

molecularly imprinted polymers ; phthalates ; methyl methacrylate ; trimethylolpropane trimethacrylate polimery z nadrukiem molekularnym ; ftalany ; poli(metakrylan metylu) ; trimetakrylan trimetylolopropanu

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Fauziah, S., Soekamto, N. H., Prastawa, B., Rasyid, H., Haedar, N., Hustim, M., Marlina, M., Sulaiman, M., & Sapar, A. (2023). Synthesis of molecularly printed methyl methacrylate-based polymers for the detection of di(2-ethylhexyl) phthalate and dibutyl phthalate. Polimery, 68(7-8), 413-423. https://doi.org/10.14314/polimery.2023.7.7

References

Luís C, Algarra M, Câmara JS, Perestrelo R., Toxics. 2021, 9(7):157.
Crossref Google Scholar

Kumari A, Kaur R, PeerJ., 2022,10:e12859.
Crossref Google Scholar

Esteki F, Karimi H, Moazeni M, Esfandiari Z, Zarean M, Pourzamani H, Iran. Journal of food quality and hazards control, 2021, 8(2):66–70.
Crossref Google Scholar

Abdul Rasid H, Ungku Zainal Abidin UF, Jinap S, Omar S, Sanny M., Pertanika Journal of Tropical Agricultural Science, 2021, 44(2):389–400.
Crossref Google Scholar

Wang Y, Qian H., Healthcare (Basel), 2021, 9(5):603.
Crossref Google Scholar

V. Prevarić, M. Sigurnjak Bureš, M. Cvetnić, M. MiloloŢa, D. Kučić Grgić, M. Markić, K. Bule, M. Milković, T. Bolanča, and Š. Ukić, Chem. Biochem. Eng. Q., 35 (2) 81–104 (2021).
Crossref Google Scholar

Yufeng Miao, Runhuai Wang, Chan Lu, Jinping Zhao, and Qihong Deng, Environmental Science and Pollution Research, 2017, vol. 24, pages 312–320.
Crossref Google Scholar

Zhang Z, Luo L, Cai R, Chen H., Biosens Bioelectron, 2013, 49: 367–73.
Crossref Google Scholar

Yang Y, Yu J, Yin J, Shao B, Zhang J., J Agric Food Chem., 2014, 62(46):11130–7.
Crossref Google Scholar

Vasapollo G, Sole RD, Mergola L, Lazzoi MR, Scardino A, Scorrano S, et al., International Journal of Molecular Sciences, 2011, 12(9):5908–45.
Crossref Google Scholar

Hashemi-Moghaddam H, Rahimian M, Niromand B., Bulletin of the Korean Chemical Society, 2013, 34(8):2330–4.
Crossref Google Scholar

Yulianti ES, Rahman SF, Whulanza Y., Biosensors, 2022, 12(12):1090.
Crossref Google Scholar

Beduk T, Gomes M, De Oliveira Filho JI, Shetty SS, Khushaim W, Garcia-Ramirez R, Durmus C, Ait Lahcen A and Salama KN, Front. Chem., 2022, 10:833899.
Crossref Google Scholar

Kirsch, N., Alexander, C., Lubke, M., Whitcombe, M.J., and Vulfson, E.N., Polymer, 2000, 14: 5583-5590.
Crossref Google Scholar

Yan H, Row KH., International Journal of Molecular Sciences, 2006, 7(5):155–78.
Crossref Google Scholar

Golker K, Karlsson B, Rosengren A, Nicholls I., IJMS, 2014, 15(11):20572–84.
Crossref Google Scholar

Hasanah AN, Dwi Utari TN, Pratiwi R., Journal of Analytical Methods in Chemistry, 2019:e9853620.
Crossref Google Scholar

Hasanah AN, Susanti I, Mutakin M., Molecules, 2022, 27(9):2880.
Crossref Google Scholar

Shahiri Tabarestani M, Rahnama K, Jahanshahi M, Nasrollanejad S, Fatemi MH., Journal of Nanostructures, 2016, 6(3):245–9.
Crossref Google Scholar

Yang, Z., Chen, F., Tang, Y., and Li, S., Journal of the Chemical Society of Pakistan, 2015, 37(5): 939- 949 Google Scholar

Zhou, T., Tao, Y., and Jin, H., 2016, Fabrication of A Selective and Sensitive Sensor Based on Molecularly Imprinted Polymer/Acetylene Black for the Determination Of Azithromycin in Pharmaceuticals and Biological Samples, 1-15.
Crossref Google Scholar

Yusof, N.A., Appribeyan, M.D., and Harson, J., Sains Malaysiana, 2010, 39(5): 829-835. Google Scholar

Dai, C., Zhang, J., Zhang, Y., Zhou, X., and Liu, S., Plos One, 2013, 8(10): 1-8.
Crossref Google Scholar

Ramakrishna, D.M., and Viraraghavan, T., Water Air and Soil Pollution, 1997, 166(1): 49-63. Google Scholar

Metwally, M.G.; Benhawy, A.H.; Khalifa, R.M.; El Nashar, R.M.; Trojanowicz, M., Molecules, 2021, 26, 6515.
Crossref Google Scholar

Zhan Yang, Fangyan Chen, Yubin Tang and Shaoli Li, J.Chem.Soc.Pak., 2015, Vol. 37, No. 05. Google Scholar

Hui Yang, Hong-Bo Liu, Zhi-Shu Tang, Zhi-Dong Qiu, Hua-Xu Zhu, Zhong-Xing Song, Ai-Ling Jia, Journal of Environmental Chemical Engineering, 2021, 9, 106352.
Crossref Google Scholar

Kusumkar, V.V., Galamboš, M., Viglašová, E., Daňo, M., Šmelková, J., Materials, 2021, 14, 1083.
Crossref Google Scholar

Shaikh H, Memon N, Khan H, Bhanger MI, Nizamani SM, Journal of Chromatography A., 2012 Jul 20,1247:125–33.
Crossref Google Scholar

Jin YF, Zhang YJ, Zhang YP, Chen J, Zhou XM, Bai LY., Journal of Chemistry, 2013 Mar 13:e903210.
Crossref Google Scholar

Hu Li, Hongming Tang, and Majia Zheng, Minerals, 2019, 9, 548.
Crossref Google Scholar

Chrisnandari, R.D., Journal of Pharmacy and Science, 2018, 3(1). Google Scholar

St. Fauziah, F.A. Sullahi, N.H. Soekamto, P. Taba, and A. Sapar, Asian Journal of Chemistry, 2021, Vol. 33, No. 4: 785-788.
Crossref Google Scholar

Febrianto, J., Kosasih, A.N., Sunarso, J., Ju, Y., Indraswati, N., and Ismadji, S., Haz. Mat. J., 2009, 162: 618..
Crossref Google Scholar

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St. Fauziah stfauziah@unhas.ac.id
https://orcid.org/0000-0002-0599-4011

Affiliation
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

Nunuk Hariani Soekamto
https://orcid.org/0000-0001-8281-1752

Affiliation
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

Budi Prastawa
https://orcid.org/0000-0002-1266-5232

Affiliation
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

Herlina Rasyid
https://orcid.org/0000-0001-9136-9716

Affiliation
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

Nur Haedar
https://orcid.org/0000-0002-6200-298X

Affiliation
Department of Biology, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

Muralia Hustim
https://orcid.org/0000-0001-8323-1549

Affiliation
Department of Environmental Engineering, Faculty of Engineering, University of Hasanuddin, Makassar, 90245 Indonesia

Marlina Marlina
https://orcid.org/0009-0008-0629-7614

Affiliation
Hasanuddin University

Bio Statement (e.g., department and rank)

Department of Chemistry

Magfirah Sulaiman
https://orcid.org/0009-0009-5156-7844

Affiliation
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

Ajuk Sapar
https://orcid.org/0000-0002-7278-6159

Affiliation
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Tanjungpura, Pontianak, 78124 Indonesia