Recent advances in modeling of polymer melt rheology

M. H. Wagner; V. H. Rolón-Garrido

doi:10.14314/polimery.2015.603

Published : 2015-10-30

Vol. 60 No. 10 (2015)

Recent advances in modeling of polymer melt rheology

M. H. Wagner V. H. Rolón-Garrido

DOI: https://doi.org/10.14314/polimery.2015.603

Abstract

To understand the link between polymerisation of aspecific monomer and the product properties, it is extremely helpful to perform arheological characterization under conditions as close as possible to those occuring in industry. Areliable rheological constitutive equation with as less free parameters as possible is also extremely necessary to reproduce accurately the experimental results obtained for abroad variety of polymer samples at different types of deformations. This allows the establishment of quantitative structure-property relations and permits simulations for specific polymer processes by numerical methods. It is the main objective of the present work to stress the role of rheology in melt processing in the framework of the rheotens experiment, and to give an overview about recent advances in modeling of polymer melt rheology. We discuss grandmastercurves obtained from the rheotens curves, as well as the rupture stress of polymer melts. In the context of rheological constitutive equations, we remind of the limitations of the rubber like-liquid and Doi-Edwards models. The introduction of the interchain tube pressure concept into the molecular stress function (MSF) model is explained. This approach permits to describe quantitatively the transient and steady-state uniaxial viscosities as well as the shear flow response of different nearly monodisperse linear polymers, without any free parameter.

Keywords

rheotens ; rheology ; constitutive equation ; Doi-Edwards tube model ; MSF model rheotens ; reologia ; równanie konstytutywne ; model rurkowy Doi-Edwardsa ; model MSF

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Wagner, M. H., & Rolón-Garrido, V. H. (2015). Recent advances in modeling of polymer melt rheology. Polimery, 60(10), 603-611. https://doi.org/10.14314/polimery.2015.603

References

van Ruymbeke E., Keunings R., Bailly C.: Journal of Non-Newtonian Fluid Mechanics 2002, 105 (2—3), 153. Article Number: PII:S0377-0257(02)00080-0

[2] Lohse D.J., Milner S.T., Fetters L.J. et al.: Macromolecules 2002, 35, 3066.
Crossref

[3] Baumgaertel M., Schausberger A., Winter H.H.: Rheologica Acta 1990, 29, 400.
Crossref

[4] Yamaguchi M., Suzuki K.: Journal of Applied Polymer Science 2002, 86, 79.
Crossref

[5] Münstedt H., Kurzbeck S., Stange J.: Polymer Engineering & Science 2006, 46 (9), 1190.
Crossref

[6] Spitael P., Macosko Ch.W.: Polymer Engineering & Science 2004, 44 (11), 2090.
Crossref

[7] Satoh N., Tomiyama H., Kajiwara T.: Polymer Engineering & Science 2001, 41(9), 1564.
Crossref 10.1002/pen.20214

[8] Burghelea T.I., Grieß H.J., Münstedt H.: Journal of Non-Newtonian Fluid Mechanics 2012, (173—174), 87.
Crossref

[9] Wagner M.H., Rolón-Garrido V.H.: Journal of Rheology 2012, 56 (5), 1279.
Crossref

[10] Wagner M.H., Rolón-Garrido V.H.: e-rheo-iba 2013, 1, 19.

[11] Meissner J.: Rheologica Acta 1971, 10, 230.
Crossref

[12] Wagner M.H., Bernnat A., Schulze V.: Journal of Rheology 1998, 42 (4), 917.
Crossref

[13] Wagner M.H., Bastian H., Bernnat A. et al.: Rheologica Acta 2002, 41, 316.
Crossref

[14] Muke S., Ivanov I., Kao N., Bhattacharya S.N.: Journal of Non-Newtonian Fluid Mechanics 2001, 101, 77. Article Number: PII: S0377-0257(01)00142-2

[15] Petrie C.J.S.: Journal of Non-Newtonian Fluid Mechanics 1977, 2, 221.
Crossref

[16] Dealy J.M., Larson R.G.: “Structure and Rheology of Molten Polymers. From Structure to Flow Behavior and Back Again”, Hanser, Germany 2006.

[17] Bernnat A., Wagner M.H.: International Polymer Processing 1999, 14 (4), 336.
Crossref

[18] Bernnat A., Wagner M.H., Chai C.K.: International Polymer Processing 2000, 15 (3), 268.
Crossref

[19] Bernnat A.: “Polymer melt rheology and the rheotens test”. PhD Thesis, Institut für Kunststofftechnologie,Universität Stuttgart 2001.

[20] Wagner M.H., Schulze V., Goettfert A.: Kautschuk Gummi Kunststoffe 1996, 49, 38.

[21] Wagner M.H, Schulze V., Goettfert A.: Polymer Engineering and Science 1996, 36, 925.
Crossref

[22] Ghijsels A., Massardier C.H.C., Bradley R.M.: International Polymer Processing 1997, 12 (2), 147.
Crossref

[23] Wang S.Q., Drda P.A.: Macromolecules 1996, 29, 4115.
Crossref

[24] Larson R.G.: “Constitutive Equations for Polymer Melts and Solutions”, Buttherworths, USA 1988.

[25] Malkin A.Y., Isayev A.I.: “Rheology. Concepts, Methods and applications”, ChemTec Publishing, Toronto, Kanada 2006.

[26] Ferry J.D.: “Viscoelastic properties of polymers”, John Wiley and Sons, USA 1980.

[27] Wagner M.H.: Rheologica Acta 1976, 15, 133.
Crossref

[28] Wagner M.H.: Rheologica Acta 1976, 15, 136.
Crossref

[29] Dealy J.M., Wissbrun K.F.: “Melt Rheology and its Role in Plastics Processing. Theory and Applications”, Kluver Academic Publishers, Netherlands 1999.

[30] Bach A., Almdal K., Rasmussen H.K., Hassager O.: Macromolecules 2003, 36, 5174.
Crossref

[31] Rolón-Garrido V.H., Wagner M.H.: Rheologica Acta 2009, 48, 245.
Crossref

[32] Doi M., Edwards S.F.: “Theory of Polymer Dynamics”, Oxford University Press, Great Britain 1986.

[33] Wagner M.H.: Rheologica Acta 1990, 29, 594.
Crossref

[34] Wagner M.H.: Makromolekulare Chemie. Macromolecular Symposia 1992, 56, 13.
Crossref

[35] Wagner M.H., Schaeffer J.: Journal of Rheology 1992, 36 (1), 1.
Crossref

[36] Wagner M.H., Rubio P., Bastian H.: Journal of Rheology 2001, 45(6), 1387.
Crossref

[37] Rolón-Garrido V.H.: Rheologica Acta 2014, 53, 663.
Crossref

[38] Pearson D.S., Kiss A.D., Fetters L.J., Doi M.: Journal of Rheology 1989, 33 (3), 517.
Crossref

[39] Pearson D.S., Kiss A.D., Fetters L.J., Doi M.: Journal of Rheology 1990, 34 (4), 613. (Erratum: [38])
Crossref

[40] Wagner M.H., Rolón-Garrido V.H.: Korea-Australia Rheology Journal 2009, 21 (4), 203.

[41] Osaki K., Nishizawa K., Kurata M.: Macromolecules 1982, 15, 1068.
Crossref

[42] Menezes E.V., Graessley W.W.: Journal of Polymer Science Part B: Polymer Physics 1982, 20, 1817.
Crossref

[43] Takahashi M., Isaki T., Takigawa T., Masuda T.: Journal of Rheology 1993, 37, 827.
Crossref

[44] Isaki T., Takahashi M., Urakawa O.: Journal of Rheology 2003, 47, 1201.
Crossref

[45] Marrucci G., Ianniruberto G.: Macromolecules 2004, 37, 3934.
Crossref

[46] Wagner M.H., Kheirandish S., Hassager O.: Journal of Rheology 2005, 49, 1317.
Crossref

[47] Rolón-Garrido V.H.,Wagner M.H., Luap C., Schweizer T.: Journal of Rheology 2006, 50 (3), 327.
Crossref

[48] Wagner M.H., Rolón-Garrido V.H.: Rheologica Acta 2010, 49, 459.
Crossref

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M. H. Wagner manfred.wagner@tu-berlin.de

Affiliation
Berlin Institute of Technology (TU Berlin), Fasanenstrasse 90, D-10623 Berlin, Germany

V. H. Rolón-Garrido

Affiliation
Berlin Institute of Technology (TU Berlin), Fasanenstrasse 90, D-10623 Berlin, Germany