Effect of self-heating during processing of rigid and plasticized poly(vinyl chloride) on its thermal stability

I. D. Simonov-Emelianov; A. V. Markov; N. I. Prokopov; I. A. Gritskova; N. I. Munkin; L. Hexel

Published : 2013-09-30

Vol. 58 No. 9 (2013)

Effect of self-heating during processing of rigid and plasticized poly(vinyl chloride) on its thermal stability

I. D. Simonov-Emelianov A. V. Markov N. I. Prokopov I. A. Gritskova N. I. Munkin L. Hexel

Abstract

Times of dynamic thermal stability ( t) depending on real temperatures of poly(vinyl chloride) (PVC) melts with different viscosities were investigated and compared. The experimental data were analyzed using the Arrhenius equation and the activation energy of PVC dehydrochlorination was determined. It was found that increased thermal stability of the melts caused by plasticization is related to a decrease in their self-heating.

Keywords

poly(vinyl chloride) ; thermal stability ; composition ; plasticization poli(chlorek winylu) ; stabilność termiczna ; kompozycje ; uplastycznianie

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Simonov-Emelianov, I. D., Markov, A. V., Prokopov, N. I., Gritskova, I. A., Munkin, N. I., & Hexel, L. (2013). Effect of self-heating during processing of rigid and plasticized poly(vinyl chloride) on its thermal stability. Polimery, 58(9), 703-706. Retrieved from http://ichp.vot.pl/index.php/p/article/view/779

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I. D. Simonov-Emelianov polimery@ichp.pl

Affiliation
Moscow State University of Fine Chemical Technologies, pr. Vernadskogo, 86, Moscow, 119571 Russia

A. V. Markov

Affiliation
Moscow State University of Fine Chemical Technologies, pr. Vernadskogo, 86, Moscow, 119571 Russia

N. I. Prokopov

Affiliation
Moscow State University of Fine Chemical Technologies, pr. Vernadskogo, 86, Moscow, 119571 Russia

I. A. Gritskova

Affiliation
Moscow State University of Fine Chemical Technologies, pr. Vernadskogo, 86, Moscow, 119571 Russia

N. I. Munkin

Affiliation
ZAO Complex pro, r. Dmitrovskoe, 87, Moscow, 127238 Russia

L. Hexel

Affiliation
BH Industries Project Sp. z o.o., Racławicka 131/35, 02-117 Warszawa, Poland