Synthesis and characterization of thermosetting resins based on 4-(N-maleimidophenylester) hydroxypropylmethacrylate

F. Mustata; I. Bicu

Published : 2010-08-30

Vol. 55 No. 7-8 (2010)

Synthesis and characterization of thermosetting resins based on 4-(N-maleimidophenylester) hydroxypropylmethacrylate

F. Mustata I. Bicu

Abstract

A hybrid monomer on 4-(N-maleimidophenylester) hydroxypropylmethacrylate (MPEHPM) possessing both maleimide and methacrylate groups has been synthesized from 4-N-carboxyphenylmaleimide (CPMI) and glycidylmethacrylate (GMA) in the presence of triethylbenzylamonium chloride (TEBAC) as a catalyst. The monomer was modified with diamino-diphenylmethanebismaleimide (MDABMI) and diglycidyl bisphenol A (DGEBA) and cured in the presence of 4,4'-methylenedianiline (MDA). The presence of an epoxy ring, amino groups and the both types of double bonds, makes these systems potential materials for obtaining thermosetting products. The curing and thermal stability of the crosslinked products were studied by differential scanning calorimetry (DSC) and TGA techniques.

Keywords

ester 4-(N-maleimidofenylowy) metakrylanu hydroksypropylowego ; właściwości termiczne ; energia aktywacji (N-maleimidophenylester) hydroxypropylmethacrylate ; thermal properties ; activation energy

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Mustata, F., & Bicu, I. (2010). Synthesis and characterization of thermosetting resins based on 4-(N-maleimidophenylester) hydroxypropylmethacrylate. Polimery, 55(7-8), 552-561. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1040

References

Lee H., Neville K.: “Handbook of epoxy resins”, McGraw-Hill, New York 1967.

2. Penn L. S., Chiao T. T.: “Epoxy resin” in “Handbook of composites” (Ed. Lubin G.), Van Nostrand Reinhold, New York 1982, pp. 57-88.

3. Flick E. W.: “Epoxy resins, curing agents, compound and modifiers”, Noyes Publications, Park Ridge, NJ 1987.

4. Sroog C. E.: “History of the invention and development of the polyimides” in “Polyimides: Fundamentals and Applications” (Eds. Ghosh M. K., Mittal K. L.), Marcel Dekker, New York 1996, pp. 1-6.

5. Park J. O., Tang T. S.: J. Polym. Sci. Part A: Polym. Chem. 1992, 30, 723.

6. Rao B. S.: J. Polym. Sci. Part C: Polym. Lett. 1988, 26, 3.

7. Ichino T., Hasuda Y: J. Appl. Polym. Sci. 1987, 34, 1667.

8. Matinez P. A., Cadiz V., Mantecon A., Serra A.: Angew. Makromol. Chem. 1985, 133, 97.

9. Mantecon A., Cadiz V., Serra A., Martinez P. A.: Angew. Makromol. Chem. 1988, 156, 37.

10. Park S. J., Kim H. C., Lee H. I., Suh D. H.: Macromolecules 2001, 34, 7573.

11. Yang N. C., Jeong J. K., Suh D. H.: Polymer Preprints 2001, 42, 535.

12. Wu C. S., Liu Y. L., Hsu K. Y.: Polymer 2003, 44, 565.

13. Chiu Y. S., Liu Y. L., Wei W. L., Chen W. Y: J. Polym. Sci. Part A: Polym. Chem. 2003, 41, 432.

14. White L. A, Weber J. W, Mathias L. J.: Polym. Bull. 2001, 46, 339.

15. Ryttel A.: Polimery 2003, 48, 695.

16. Vanaja A., Rao R. M. V. G. K.: Eur. Polym. J. 2002, 38, 187.

17. Mustata R, Bicu L: Polimery 2000, 45, 258.

18. Dix L. R., Ebdon J. R., Flint N. J., Hodge P., O’Dell R.: Eur. Polym. J. 1995, 31, 647.

19. Cascaval C. N., Mustata R, Rosu D.: Angew. Makromol Chem. 1993, 209, 157.

20. Kissinger H. R: Anal. Chem. 1957, 29, 1702.

21. Ozawa T.: J. Thermal. Anal. 1976, 9, 364.

22. Swaminathan V, Modhavan N. S.: J. Anal. Appl. Pyrolysis 1981, 3, 131.

23. Coats A. W., Redfern J. R.: Nature 1964, 201, 68.

24. Musto R, Marruscelli E., Ragosta G., Russo R, Scarinzi G.: J. Appl. Polym. Sci. 1998, 69, 1029.

25. Kumar A. A., Alagar M., Rao R. M. V. G. K.: J. Appl. Polym. Sci. 2001, 81, 2330.

26. Dinakaran K., Alagar M.: J. Appl. Polym. Sci. 2002, 85, 2853.

27. Walling C., Briggs E. R.: J. Am. Chem. Soc. 1946, 68, 1141.

28. Varma I. K., Sangita M. S., Varma D. S.: J. Polym. Sci. Polym. Chem. 1984, 22, 1419.

29. Pitchard G., Swan M.: Eur. Polym. J. 1993, 29, 357.

30. Luders G., Merker E., Raubach H.: Angew. Macromol. Chem. 1990, 182, 135.

31. Lin K. R, Chen J. C.: Polym. Eng. Sci. 1996, 36, 211.

32. Wu C.-S., Liu Y.-L., Hsu K.-Y: Polymer 2003, 44, 565.

33. Liu Y.-L., Chen Y.-J.: Polymer 2004, 45, 1797.

34. Vinayagamoorti S., Vijaayakumar C. T., Alam S., Nanjundan S.: Eur. Polym. J. 2009, 45, 1217.

35. Ren H., Sun J., Zhao Q., Zhou Q., Ling Q.: Polymer 2008, 49, 5249.

36. Mustata R, Bicu I.: Macromol. Mater. Eng. 2006, 291, 732.

37. Mustata F. R., Bicu I. Gh.: Ind. Eng. Chem. Res. 2008, 47, 1355.

Google Scholar

Citing articles via

Statistics

Total abstract views : 51

PDF Downloads : 27