Microwave-assisted synthesis and copolymerization of photo- and electroluminescent methacrylates containing carbazole and coumarin pendant groups

D. Bogdał; I. Stępień; J. Santera; E. Gondek

Published : 2022-09-17

Vol. 48 No. 2 (2003)

Microwave-assisted synthesis and copolymerization of photo- and electroluminescent methacrylates containing carbazole and coumarin pendant groups

D. Bogdał I. Stępień J. Santera E. Gondek

Abstract

2-(9-carbazolyl)ethyl methacrylate (CEM) and 7- (diethylamino)coumarin-3-carboxylic acid 2-(methacryloyloxy) ethyl ester (WK) were synthesized and then copolymerized in molar proportion (99.5:0.5), (99:1), (98:2), and (92:8 mol/mol) to give CEM/MK copolymers. Starting materials for monomers synthesis: N-(2-hydroxyethyl)carbazole and 7- (diethyloamino)coumarin-3-carboxylic acid were synthesized under microwave irradiation using novel modified methods. Solutions of the copolymers in THF were examined for their photoluminescence properties, while thin films made of the copolymers for electroluminescence properties.

Keywords

metakrylany zawierające pochodne karbazolu i kumaryny ; synteza ; promieniowanie mikrofalowe ; kopolimeryzacja ; fotoluminescencja ; elektroluminescencja carbazole ; coumarin ; microwave irradiation ; photoluminescence ; electroluminescence

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Bogdał, D., Stępień, I., Santera, J., & Gondek, E. (2022). Microwave-assisted synthesis and copolymerization of photo- and electroluminescent methacrylates containing carbazole and coumarin pendant groups. Polimery, 48(2), 111–115. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1844

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D. Bogdał polimery@ichp.pl

Affiliation
Cracow University of Technology, Department of Chemistry, ul. Warszawska 24, 31-155 Kraków, Poland Cracow University of Technology, Department of Physics, ul. Podchorążych 1, 30-840, Poland

I. Stępień

J. Santera

E. Gondek