Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers

P. Parcheta; I. Koltsov; E. Głowińska; J. Datta

doi:10.14314/polimery.2018.10.6

Published : 2021-01-13

Vol. 63 No. 10 (2018)

Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers

P. Parcheta I. Koltsov E. Głowińska J. Datta

DOI: https://doi.org/10.14314/polimery.2018.10.6

Abstract

Linear bio-based polyester polyols were prepared with the use of succinic acid and 1,3-propanediol (both with natural origin). Tetraisopropyl orthotitanate (TPT) was used as a catalyst. In order to determine the effect of various synthesis temperature conditions on the thermal degradation kinetics, nine sequences of temperature conditions were used during two-step polycondensation reaction. Thermogravimetric analysis was conducted with the use of DSC-TG/QMS method (differential scanning calorimetry-coupled with thermogravimetry and quadrupole mass spectrometry). The results indicated high thermal stability of the obtained materials. They undergo a one-step thermal decomposition with the temperature of maximum rate of weight loss at ca. 405 °C. Moreover, the thermal degradation kinetics was determined with the use of Ozawa, Flynn and Wall as well as Kissinger methods. The highest thermal degradation activation energy was equal to 196.4 kJ/mol.

Keywords

poly(propylene succinate) ; bio-based polyester ; thermal degradation kinetics ; Ozawa method ; Flynn method ; Wall method ; Kissinger method poli(bursztynian propylenu) ; biopoliol poliestrowy ; kinetyka degradacji termicznej ; metoda Ozawy Flynna i Walla ; metoda Kissingera

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Parcheta, P., Koltsov, I., Głowińska, E., & Datta, J. (2021). Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers. Polimery, 63(10), 700-707. https://doi.org/10.14314/polimery.2018.10.6

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P. Parcheta help@libcom.pl

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80-233 Gdańsk, Poland

I. Koltsov

Affiliation
Polish Academy of Sciences, Institute of High Pressure Physics, Laboratory of Nanostructures for Photonic and Nanomedicine, Sokołowska 29/37, 01-142 Warszawa, Poland

E. Głowińska

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80-233 Gdańsk, Poland

J. Datta

Affiliation
Gdańsk University of Technology, Faculty of Chemistry, Department of Polymers Technology, G. Narutowicza 11/12, 80-233 Gdańsk, Poland