The complementary structural studies of the double metal cyanide type catalysts for the ring opening polymerization of the oxiranes

A. Chruściel; W. Hreczuch; K. Czaja; K. Ławniczak-Jabłońska; J. Janik

doi:10.14314/polimery.2016.421

Published : 2021-01-24

Vol. 61 No. 6 (2016)

The complementary structural studies of the double metal cyanide type catalysts for the ring opening polymerization of the oxiranes

A. Chruściel W. Hreczuch K. Czaja K. Ławniczak-Jabłońska J. Janik

DOI: https://doi.org/10.14314/polimery.2016.421

Abstract

The extensive complementary experimental studies of the double metal catalysts (DMC) with two kinds of the organic ligands were performed. The chemical justification of the observed TG/DSC (thermogravimetric analysis/differential scanning calorimetry) steps was proposed. Several organic ligand complexing states were found in both types of catalysts. X-ray absorption spectroscopy (XAS) analysis established that only Zn atoms are the active metallic centers in DMC catalyst regardless the used ligand. Cl atoms were detected near some of Zn atoms. Contrary to the common suppositions no significant amount of oxygen atoms was detected in the closest coordination spheres of Zn.

Keywords

double metal cyanide catalysts (DMC) ; thermal analysis ; thermogravimetric analysis (TG) ; differential scanning calorimetry (DSC) ; evolved gas analysis (EGA) ; X-ray absorption spectroscopy (XAS) ; X-ray absorption near edge structure (XANES) ; extended X-ray absorption fine structure (EXAFS) katalizatory dimetalocyjankowe (DMC) ; analiza termiczna ; analiza termograwimetryczna (TGA) ; różnicowa kalorymetria skaningowa (DSC) ; analiza wydzielanych gazów (EGA) ; rentgenowska absorpcyjna spektroskopia struktury przykrawędziowej (XANES) ; synchrotronowa absorpcyjna spektroskopia rentgenowska (EXAFS)

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Chruściel, A., Hreczuch, W., Czaja, K., Ławniczak-Jabłońska, K., & Janik, J. (2021). The complementary structural studies of the double metal cyanide type catalysts for the ring opening polymerization of the oxiranes. Polimery, 61(6), 421-432. https://doi.org/10.14314/polimery.2016.421

References

Bailey F.E., Koleske J.V.: “Surfactant Science Series”, Vol. 35, Marcel Dekker, Inc., New York and Basel, 1991.

[2] Ionescu M.: “Chemistry and Technology of Polyols for Polyurethanes”, R.A.P.R.A. Technology Ltd. Shawbury-Shrewsbury-Shropshire, UK 2005.

[3] Chruściel A., Hreczuch W., Janik J. et al.: Industrial and Engineering Chemistry Research 2014, 53, 6636.
Crossref

[4] Kim I., Ahn J.-T., Ha Ch.-S. et al.: Polymer 2003, 44, 3417.
Crossref

[5] Chen S., Zhang P., Chen L.: Progress in Organic Coatings 2004, 50, 269.
Crossref

[6] Kim I., Byun S.H., Ha C.S.: Journal of Polymer Science Part A: Polymer Chemistry 2005, 43, 4393.
Crossref

[7] Lee S., Baek S., Anas T.K. et al.: Polymer 2007, 48, 4361.
Crossref

[8] Zhang X.-H., Hua Z.-J., Chen Sh. et al.: Applied Catalysis A: General 2007, 325, 91.
Crossref

[9] Huang Y.-J., Zhang X.-H., Hua Z.-J. et al.: Macromolecular Chemistry and Physics 2010, 11, 1229.
Crossref

[10] van der Kerk G.J.M.: Pure and Applied Chemistry 1972, 30 (3–4), 389.
Crossref

[11] Wells A.F.: “Structural Inorganic Chemistry Oxford University Press”, 1984.

[12] Huang Y.J., Qi G.R., Chen L.Sh.: Applied Catalysis A: General 2003, 240, 263.
Crossref

[13] Liu H., Wang X., Gu Y., Guo W.: Molecules 2003, 8, 67.
Crossref

[14] Kim I., Ahn J.-T., Lee S.-H. et al.: Catalysis Today 2004, 93, 511.
Crossref

[15] Yoon J.H., Lee I.K., Choi H.Y. et al.: Green Chemistry 2011, 13, 631.
Crossref

[16] Lawniczak-Jabłońska K., Demchenko I., Dynowska E. et al.: Acta Crystallographica 2014, A70, C592.
Crossref

[17] Lawniczak-Jabłonska K., Dynowska E., Lisowski W. et al.: X-ray Spectrometry 2015, 44, 330.
Crossref

[18] Sebastian J., Srinivas D.: Applied Catalysis A: General 2014, 482, 300.
Crossref

[19] Lee I.K., Ha J.Y., Cao Ch. et al.: Catalysis Today 2009, 148, 389.
Crossref

[20] Šutinska V., Patjášová M., Ondrušová D. et al.: Journal of Thermal Analysis and Calorimetry 2011, 104, 923.
Crossref

[21] Zhou T., Zou Zh., Gan J. et al.: Journal of Polymer Research 2011, 18, 2071.
Crossref

[22] Wojdeł J.C., Bromley S.T., Illas F., Jansen J.C.: Journal of Molecular Modeling 2007, 13, 751.
Crossref

[23] Almora-Barrios N., Pogodin S., Bellarosa L. et al.: ChemCatChem Catalysis 2015, 7, 928.
Crossref

[24] Rodríguez-Hernández J., Reguera E., Lima E. et al.: Journal of Physics and Chemistry of Solids 2007, 68, 1630.
Crossref

[25] Barnard J.A.: Transactions of the Faraday Society 1959, 55, 947.
Crossref

[26] Ponrouch A., Marchante E., Courty M. et al.: Energy and Environmental Science 2012, 5, 8572.
Crossref

Remove [1] Bailey F.E., Koleske J.V.: “Surfactant Science Series”, Vol. 35, Marcel Dekker, Inc., New York and Basel, 1991.

[2] Ionescu M.: “Chemistry and Technology of Polyols for Polyurethanes”, R.A.P.R.A. Technology Ltd. Shawbury-Shrewsbury-Shropshire, UK 2005.

[3] Chruściel A., Hreczuch W., Janik J. et al.: Industrial and Engineering Chemistry Research 2014, 53, 6636.
Crossref

[4] Kim I., Ahn J.-T., Ha Ch.-S. et al.: Polymer 2003, 44, 3417.
Crossref

[5] Chen S., Zhang P., Chen L.: Progress in Organic Coatings 2004, 50, 269.
Crossref

[6] Kim I., Byun S.H., Ha C.S.: Journal of Polymer Science Part A: Polymer Chemistry 2005, 43, 4393.
Crossref

[7] Lee S., Baek S., Anas T.K. et al.: Polymer 2007, 48, 4361.
Crossref

[8] Zhang X.-H., Hua Z.-J., Chen Sh. et al.: Applied Catalysis A: General 2007, 325, 91.
Crossref

[9] Huang Y.-J., Zhang X.-H., Hua Z.-J. et al.: Macromolecular Chemistry and Physics 2010, 11, 1229.
Crossref

[10] van der Kerk G.J.M.: Pure and Applied Chemistry 1972, 30 (3–4), 389.
Crossref

[11] Wells A.F.: “Structural Inorganic Chemistry Oxford University Press”, 1984.

[12] Huang Y.J., Qi G.R., Chen L.Sh.: Applied Catalysis A: General 2003, 240, 263.
Crossref

[13] Liu H., Wang X., Gu Y., Guo W.: Molecules 2003, 8, 67.
Crossref

[14] Kim I., Ahn J.-T., Lee S.-H. et al.: Catalysis Today 2004, 93, 511.
Crossref

[15] Yoon J.H., Lee I.K., Choi H.Y. et al.: Green Chemistry 2011, 13, 631.
Crossref

[16] Lawniczak-Jabłońska K., Demchenko I., Dynowska E. et al.: Acta Crystallographica 2014, A70, C592.
Crossref

[17] Lawniczak-Jabłonska K., Dynowska E., Lisowski W. et al.: X-ray Spectrometry 2015, 44, 330.
Crossref

[18] Sebastian J., Srinivas D.: Applied Catalysis A: General 2014, 482, 300.
Crossref

[19] Lee I.K., Ha J.Y., Cao Ch. et al.: Catalysis Today 2009, 148, 389.
Crossref

[20] Šutinska V., Patjášová M., Ondrušová D. et al.: Journal of Thermal Analysis and Calorimetry 2011, 104, 923.
Crossref

[21] Zhou T., Zou Zh., Gan J. et al.: Journal of Polymer Research 2011, 18, 2071.
Crossref

[22] Wojdeł J.C., Bromley S.T., Illas F., Jansen J.C.: Journal of Molecular Modeling 2007, 13, 751.
Crossref

[23] Almora-Barrios N., Pogodin S., Bellarosa L. et al.: ChemCatChem Catalysis 2015, 7, 928.
Crossref

[24] Rodríguez-Hernández J., Reguera E., Lima E. et al.: Journal of Physics and Chemistry of Solids 2007, 68, 1630.
Crossref

[25] Barnard J.A.: Transactions of the Faraday Society 1959, 55, 947.
Crossref

[26] Ponrouch A., Marchante E., Courty M. et al.: Energy and Environmental Science 2012, 5, 8572.
Crossref

Google Scholar

Altmetric indicators

Citing articles via

CITEDBY SCOPUS

Statistics

Total abstract views : 117

PDF Downloads : 53

A. Chruściel arkach@mexeo.pl

Affiliation
MEXEO Institute of Technology, Energetyków 9, 47-225 Kędzierzyn-Koźle, Poland

W. Hreczuch

Affiliation
MEXEO Institute of Technology, Energetyków 9, 47-225 Kędzierzyn-Koźle, Poland

K. Czaja

Affiliation
University of Opole, Faculty of Chemistry, Oleska 48, 45-052 Opole, Poland

K. Ławniczak-Jabłońska

Affiliation
Institute of Physics, Polish Academy of Sciences, Lotników 32/46, 02-668 Warsaw, Poland

J. Janik

Affiliation
MEXEO Institute of Technology, Energetyków 9, 47-225 Kędzierzyn-Koźle, Poland