A controlled radical polymerization route to polyepoxidated grafted hemicellulose materials

U. Edlund; A.-Ch. Albertsson

doi:10.14314/polimery.2014.060

Published : 2014-01-30

Vol. 59 No. 1 (2014)

A controlled radical polymerization route to polyepoxidated grafted hemicellulose materials

U. Edlund A.-Ch. Albertsson

DOI: https://doi.org/10.14314/polimery.2014.060

Abstract

Polyfunctional copolymers were prepared from the major softwood hemicellulose polysaccharide, i.e. O-acetylated galactoglucomannan (AcGGM) through a grafting-from controlled radical polymerization. AcGGM was functionalized with brominated pendant groups that served as initiating species in the subsequent Cu(0) mediated radical polymerization of glycidyl methacrylate (GMA). A linear relationship of ln[GMA]0/[GMA] (the index 0 refers to the initial value) versus reaction time up to conversions of 80 % suggests a first order rate of propagation and a "living” polymerization.

Keywords

O-acetylated galactoglucomannan ; hemicellulose ; renewable resources ; single-electron-transfer living radical polymerization O-acetylowany galaktoglukomannan hemiceluloza ; surowce odnawialne ; rodnikowa polimeryzacja ; żyjąca z przeniesieniem pojedynczego elektronu.

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Zasady cytowania

Edlund, U., & Albertsson, A.-C. (2014). A controlled radical polymerization route to polyepoxidated grafted hemicellulose materials. Polimery, 59(1), 60–65. https://doi.org/10.14314/polimery.2014.060

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U. Edlund polimery@ichp.pl

Affiliation
Royal Institute of Technology (KTH), Fibre and Polymer Technology, Teknikringen 56, SE-100 44 Stockholm, Sweden

A.-Ch. Albertsson

Affiliation
Royal Institute of Technology (KTH), Fibre and Polymer Technology, Teknikringen 56, SE-100 44 Stockholm, Sweden