Photoinduced charge separation in aqueous solution of porphyrin-quinone end-capped poly(methacrylic acid)

S. Zapotoczny; F. Kataoka; M. Nowakowska

doi:10.14314/polimery.2014.095

Published : 2014-01-30

Vol. 59 No. 1 (2014)

Photoinduced charge separation in aqueous solution of porphyrin-quinone end-capped poly(methacrylic acid)

S. Zapotoczny F. Kataoka M. Nowakowska

DOI: https://doi.org/10.14314/polimery.2014.095

Abstract

Photoinduced charge separation from porphyrin (P) to benzoquinone (Q) moieties covalently attached to the opposite chain ends of poly(methacrylic acid) (PMMA) was studied. The effect of polymer chain length, pH and ionic strength of the aqueous solution on the rate constant of charge separation and efficiency of P+• - Q-• radical ion pair formation was determined.

Keywords

poly(methacrylic acid) ; anionic polymerization ; porphyrin ; benzoquinone ; photoinduced electron transfer ; photoinduced charge-separation ; radical-ion pair ; electron paramagnetic resonance (EPR) poli(kwas metakrylowy) ; polimeryzacja anionowa ; porfiryna ; benzochinon ; fotoindukowane przenoszenie elektronu ; fotoindukowana separacja ładunku ; para rodniko-jonowa ; elektronowy rezonans paramagnetyczny (EPR)

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Zapotoczny, S., Kataoka, F., & Nowakowska, M. (2014). Photoinduced charge separation in aqueous solution of porphyrin-quinone end-capped poly(methacrylic acid). Polimery, 59(1), 95–100. https://doi.org/10.14314/polimery.2014.095

References

Marcus R. A.: J. Phys. Chem. 1965, 43, 679.

2. Weller A. Z.: Phys. Chem. (Wiesbaden) 1982, 133, 93.

3. Wasielewski M. R., Niemczyk M. P.: J. Am. Chem. Soc. 1984, 106, 5043.

4. Wasielewski M. R., Niemczyk M. P., Svec W. A., Pewitt E. B.: J. Am. Chem. Soc. 1985, 107, 1080.

5. Joran A. R., Leland B. A., Felker P. M., Zewail A. H., Hopfield J. J., Dervan P. B.: Nature 1987, 327, 508.

6. Nocera D. G.: Acc. Chem. Res. 2012, 45, 767.

7. Patwardhan S., Sengupta S., Siebbeles L. D. A., Würthner F., Grozema F. C.: J. Am. Chem. Soc. 2012, 134, 16147.

8. Springer J. W., Parkes-Loach P. S., Reddy K. R., Krayer M., Jiao J., Lee G. M., Niedzwiedzki D. M., Harris M. A., Kirmaier C., Bocian D. F., Lindsey J. S., Holten D., Loach P. A.: J. Am. Chem. Soc. 2012, 134, 4589.

9. Kloz M., Pillai S., Kodis G., Gust D., Moore T. A., Moore A. L., van Grondelle R., Kennis J. T. M.: J. Am. Chem. Soc. 2011, 133, 7007.

10. Westenhoff S., Paleèek D., Edlund P., Smith P., Zigmantas D.: J. Am. Chem. Soc. 2012, 134, 16484.

11. Fox M. A.: Adv. Photochem. 1986, 13, 237.

12. Wasielewski M. R.: Chem. Rev. 1992, 92, 435.

13. Weaver M. J.: Chem. Rev. 1992, 92, 463.

14. Guillet J. E., Takahashi Y., McIntosh A. R., Bolton J. R.: Macromolecules 1985, 18, 1788.

15. Liu G., Guillet J. E., Al-Takrity E. T. B., Jenkins A. D.,Walton D. R. M.: Macromolecules 1991, 24, 68.

16. Liu G., Guillet J. E., Vlegels M., Goethals E. J.: Macromolecules 1991, 24, 4094.

17. Nowakowska M., Kataoka F., Guillet J. E.: Macromolecules 1996, 29, 1600.

18. Nowakowska M., White B., Guillet J. E.: Macromolecules 1989, 22, 3903.

19. Wasielewski M. R., Niemczyk M. P.: J. Am. Chem. Soc. 1984, 106, 5043.

20. Sulivan P. D., Bolton J. R., Geiger Jr. W. E.: J. Am. Chem. Soc. 1970, 92, 4176.

21. Guilet J. E., Takahashi Y., McIntosh A. R., Bolton J. R.: Macromolecules 1985, 18, 1788.

22. McIntosh A. R., Siemiarczuk A., Bolton J. R., Stillman M. J., Ho T.-H., Weedon A. C.: J. Am. Chem. Soc. 1983, 105, 7224.

23. Wertz J. E., Bolton J. R.: “Electron Spin Resonance Elementary Theory and Practical Applications”, McGraw-Hill, New York 1972.

Google Scholar

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

S. Zapotoczny zapotocz@chemia.uj.edu.pl

Affiliation
Faculty of Chemistry, Jagiellonian University, 30-060 Kraków, Ingardena 3, Poland

F. Kataoka

Affiliation
Production Engineering Research Laboratory, Hitachi Ltd., 292 Yoshida-cho, Toksuka-ku, Yokohama 244, Japan

M. Nowakowska

Affiliation
Faculty of Chemistry, Jagiellonian University, 30-060 Kraków, Ingardena 3, Poland