Otrzymywanie i zastosowanie funkcjonalizowanych napełniaczy hybrydowych SiO2/F-SF POSS w żelowych elektrolitach polimerowych

K. Szwarc-Rzepka; M. Walkowiak; M. Osińska-Broniarz; M. Dutkiewicz; H. Maciejewski; T. Jesionowski

Published : 2013-10-30

Vol. 58 No. 10 (2013)

Preparation of functionalised SiO2/F-SF poss hybrid fillers and their application in gel polymer electrolytes

K. Szwarc-Rzepka M. Walkowiak M. Osińska-Broniarz M. Dutkiewicz H. Maciejewski T. Jesionowski

Abstract

Hybrid SiO2/POSS fillers were obtained using the method based on solvent evaporation. Octakis({1,1,2,2,3,3,4,4-octafluoropentyloxypropyl}dimethylsiloxy) octasilsesquioxane (F-SF POSS) was used to modify the surface of silica, hydrated or prepared via emulsion method. The effectiveness of modification was evaluated by FT-IR spectroscopy and nuclear magnetic resonance (29Si and 13C CP MAS NMR). The parameters of porous structure of the prepared hybrid fillers, such as surface area BET, mean pore diameter and pore volume were determined. The hybrid products were subjected to dispersive analysis (non-invasive backscattering method, NIBS) and morphological characterization (using transmission electron microscopy — TEM). The obtained hybrid systems were used as additives in gel polymer electrolytes, prepared by activation of dry composite membranes in a liquid solution of lithium salt. The electrolytes were subjected to electrochemical studies, including the measurements of specific conductivity by impedance spectroscopy in a wide range of temperatures and the determination of potential windows by the linear cyclic voltammetry. The addition of POSS composites had a beneficial effect on the transport of lithium cations and the room temperature conductivity of gel electrolytes based on PVdF/HFP membranes was enhanced by an order of magnitude. The observed increase in gel conductivity was poorly correlated with the ability of liquid phase absorption. The anodic stability of gels only slightly increased upon the addition of POSS to PVdF/HFP membranes. The fillers studied show promising properties in the context of future research and development studies on new solid electrolytes for lithium cells with increased safety.

Keywords

wielościenne oligomeryczne silseskwioksany (POSS) ; SiO2 ; żelowe elektrolity polimerowe polyhedral oligomeric silsesquioxane (POSS) ; SiO2 ; gel polymer electrolytestion

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Szwarc-Rzepka, K., Walkowiak, M., Osińska-Broniarz, M., Dutkiewicz, M., Maciejewski, H., & Jesionowski, T. (2013). Preparation of functionalised SiO2/F-SF poss hybrid fillers and their application in gel polymer electrolytes. Polimery, 58(10), 748-758. Retrieved from https://ichp.vot.pl/index.php/p/article/view/782

References

Croce F., Persi L., Scrosati B., Serraiono-Fiory F., Plichta E., Hendrikson M. A.: Electrochim. Acta 2001, 46, 2457.

[2] Kumar B.: J. Power Sources 2004, 135, 215.

[3] Zhou J., Fedkiw P. S.: Solid State Ionics 2004, 166, 275.

[4] Stephan A. M., Nahm K. S.: Polymer 2006, 47, 5952.

[5] Song J. Y.,Wang Y. Y.,Wan C. C.: J. Power Sources 1999, 77, 183.

[6] Stephan A. M.: Eur. Polym. J. 2006, 42, 21.

[7] Qianqian Ou Q., Zhou L., Zhao S., Geng H., Hao J., Xu Y., Chen H., Chen X.: Chem. Eng. J. 2012, 180, 121.

[8] Zhou J., Fedkiw P. S.: Solid State Ionics 2004, 166, 275.

[9] Shi Q., Yu M., Zhou X., Yan Y., Wan C.: J. Power Sources 2002, 103, 286.

[10] Capiglia C., Saito Y., Kataoka H., Kodama T., Quartarone E., Mustarelli P.: Solid State Ionics 2000, 131, 291.

[11] Caillon-Caravanier M., Claude-Montigny B., Lemordant D., Bosser G.: J. Power Sources 2002, 107, 125.

[12] Thostenson E. T., Li Ch., Chou T.W.: Compos. Sci. Technol. 2007, 65, 491.

[13] Świderski F., Robak-Waszkiewicz B.: Bromatol. Chem. Toksykol. 2008, 3, 202.

[14] Goffin A.-L., Duquesne E., Moins S., Alexandre M., Dubois Ph.: Eur. Polym. J. 2007, 43, 4103.

[15] Iyer S., Abu-Ali A., Detwiler A., Sehiraldi A.: ACS Symposium Series, Cleveland 2007, 964, 313. [16] Lickiss P. D., Rataboul F.: Adv. Organom. Chem. 2008, 57, 1.

[17] Tai Q., Yuen R. K. K., Song L., Hu Y.: Chem. Eng. J. 2012, 183, 542.

[18] Westcott S., Oldenburg S., Lee T. R., Halas N. J.: Langmuir 1998, 14, 5396.

[19] Maciejewski H., Dutkiewicz M., Byczyñski £., Marciniec B.: Polimery 2012, 57, 7.

[20] Xu H., Kuo S.-W., Lee J.-S., Chang F.-C.: Macromolecules 2002, 35, 8788.

[21] Xu H., Yang B.,Wang J., Guang S., Li C.: Macromolecules 2005, 38, 10 455.

[22] Lee A., Lichtenhan J. D.: Macromolecules 1998, 31, 4970.

[23] Fina A., Tabuani D., Peijs T., Camino G.: Polymer 2009, 50, 218.

[24] Li G. Z., Cho H., Wang L., Toghiani H., Pittman Jr. Ch. U.: J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 355.

[25] Mammeri F., Bonhomme Ch., Ribot F., Babonneau F., Diré S.: Chem. Mater. 2009, 21, 4163.

[26] Sarantopoulou E., Kollia Z., Cefalas A. C., Siokou A. E., Argitis P., Bellas V.: J. Appl. Phys. 2009, 105, 114.

[27] Xu H., Kuo S.-W., Lee J.-S., Chang F.-Ch.: Macromolecules 2002, 35, 8788.

[28] Fong H., Dickens S. H., Flaim G. M.: Dent. Mater. 2005, 21, 520.

[29] Wheeler P. A., Fu B. X., Lichtenhan J. D.,Weitao J., Mathias L. J.: J. Appl. Polym. Sci. 2006, 102, 2856.

[30] Jankiewicz B. J., Choma J., Jamioła D., Jaroniec M.: Wiad. Chem. 2010, 64, 917.

[31] Jesionowski T., Żurawska J., Krysztafkiewicz A.: J. Mater. Sci. 2002, 34, 1621.

[32] Downs T. R., Palmer D. C.: Am. Mineral. 1994, 79, 9.

[33] Bergna E. H., Roberts O.W.: „Colloidal silica: Fundamentals and Applications”, CRC Press Taylor and Francis Group, United States 2006.

[34] Iler R. K.: „The chemistry of silica”, Wiley & Sons, New York 1979.

[35] Georgakilas V., Bourlinos A. B., Zboril R., Trapalis C.: Chem. Mater. 2008, 20, 2884.

[36] Oldenburg S. J., Averitt R. D., Westcott S. L., Halas N. J.: Chem. Phys. Lett. 1998, 288, 243.

[37] Wallace W. E., Guttman C. M., Antonucci J. M.: Polymer 2000, 41, 2219.

[38] Jesionowski T., Krysztafkiewicz A., Pokora M., Waszak D., Tylus W.: Appl. Surf. Sci. 2003, 205, 212.

[39] Zurawska J., Krysztafkiewicz A., Jesionowski T.: Surf. Interface Anal. 2003, 35, 914.

[40] Jesionowski T., Ciesielczyk F., Krysztafkiewicz A.: Mater. Chem. Phys. 2010, 119, 65.

[41] Jesionowski T.: J. Mater. Process. Technol. 2008, 203, 121.

[42] VanderGheynst J., Dooley T., Guo H.-Y., Scher H., Cheng Y.-S.: Proc. Biochem. 2010, 45, 1.

[43] Morel B., Autissier L., Autissier D., Lemordant D., Yrieix B., Quenard D.: Powder Technol. 2009, 190, 225.

[44] Bogdan A., Kulmala M., Gorbunov B., Kruppa A.: J. Colloid Interface Sci. 1996, 177, 79.

[45] Stöber W., Fink A., Bohn E.: J. Colloid Interface. Sci. 1968, 26, 62.

[46] Green D. L., Lin J. S., Lam Y.-F., Hu M. Z.-C., Schaefer DaleW., Harris M. T.: J. Colloid Interface Sci. 2003, 266, 346.

[47] Nakahara Y., Takeuchi T., Yokoyama S., Kimura K.: Surf. Interface Anal. 2011, 43, 809.

[48] Dutkiewicz M., Maciejewski H., Marciniec B., Karasiewicz J.: Organometallics 2011, 30, 2149.

[49] Jesionowski T.: Mater. Chem. Phys. 2009, 113, 839.

[50] Szwarc--Rzepka K., Marciniec B., Jesionowski B.: Adsorption 2013, 19, 483.

[51] Tarascon J.-M., Gozdz A. S., Schmutz C., Shokoohi F., Warren P. C.: Solid State Ionics 1996, 86—88, 49.

[52] Szwarc-Rzepka K., Ciesielczyk F., Zawisza M., Kaczmarek M., Dutkiewicz M., Marciniec B., Maciejewski H., Jesionowski T.: Physicochem. Probl. Miner. Process. 2012, 48, 619.

Google Scholar

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 66

PDF Downloads : 95

K. Szwarc-Rzepka polimery@ichp.pl

Affiliation
Politechnika Poznańska, Wydział Technologii Chemicznej, Instytut Technologii i Inżynierii Chemicznej, pl. M. Skłodowskiej-Curie 2, 60-965 Poznań

M. Walkowiak

Affiliation
Instytut Metali Nieżelaznych Oddział w Poznaniu, Centralne Laboratorium Akumulatorów i Ogniw, ul. Forteczna 12, 61-362 Poznań

M. Osińska-Broniarz

Affiliation
Instytut Metali Nieżelaznych Oddział w Poznaniu, Centralne Laboratorium Akumulatorów i Ogniw, ul. Forteczna 12, 61-362 Poznań

M. Dutkiewicz

Affiliation
Uniwersytet im. A. Mickiewicza w Poznaniu, Wydział Chemii, Zakład Chemii Metaloorganicznej, ul. Grunwaldzka 6, 60-780 Poznań

H. Maciejewski

Affiliation
Uniwersytet im. A. Mickiewicza w Poznaniu, Wydział Chemii, Zakład Chemii Metaloorganicznej, ul. Grunwaldzka 6, 60-780 Poznań

T. Jesionowski

Affiliation
Politechnika Poznańska, Wydział Technologii Chemicznej, Instytut Technologii i Inżynierii Chemicznej, pl. M. Skłodowskiej-Curie 2, 60-965 Poznań