Chemical adsorption of liquid organochlorine compounds as a method of purification of pyrolytic oil

K. German; E. Pawlikowska; K. Kulesza

Published : 2011-01-30

Vol. 56 No. 1 (2011)

Chemical adsorption of liquid organochlorine compounds as a method of purification of pyrolytic oil

K. German E. Pawlikowska K. Kulesza

Abstract

In this work, a new method of purification of pyrolytic oil from organochlorine compounds with silver or platinum adsorbents was proposed and tested. The experiments carried out at temperatures from 20 up to 200 °C have shown that chosen for studies organochlorine compounds were well adsorbed from the prepared solutions. Eminently respectable results were found for silver adsorbent. A high initial cost of such adsorbents mandates their regeneration. It has been shown that it is possible to clear the adsorbent surface with hydrogen at the temperature 300-350 °C. A residue on the surface (after several cycles of adsorption/regeneration) can be burned with air.

Keywords

odchlorowanie oleju pirolitycznego ; adsorpcja chemiczna ; srebro ; platyna ; regeneracja dechlorination of pyrolytic oil ; chemical adsorption ; silver ; platinum ; regeneration

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Zasady cytowania

German, K., Pawlikowska, E., & Kulesza, K. (2011). Chemical adsorption of liquid organochlorine compounds as a method of purification of pyrolytic oil. Polimery, 56(1), 67-69. Retrieved from https://ichp.vot.pl/index.php/p/article/view/894

References

German K.: Polimery 2010, 55, 351.

2. Müller J., Dongmann G., Frischkorn C. G. B.: J. Anal. Appl. Pyrolysis 1997, 43, 157.

3. Lingaiah N., Uddin Md. A., Muto A., Sakata Y, Imai T., Murata K.: Appl. Catal., A 2001, 207, 79.

4. Brebu M., Bhaskar T., Murai K., Muto A., Sakata Y, Uddin Md. A.: Polym. Degrad. Stab. 2005, 87, 225.

5. Hinz B., Hoffmockel M., Pohlmann K., Schadel S., Schimmel I., Sinn H.: J. Anal. Appl. Pyrol. 1994, 30, 35.

6. Lunin V. V., Lokteva E. S.: Iz. Akad. Nauk. Ser. Khim. 1996, No. 7, 1609.

7. Tavoularis G., Keane M. A.: J. Mol. Catal. A.: Chem. 1999, 142, 187.

8. Bhaskar T., Kaneko J., Muto A., Sakata Y, Jakab E., Matsui T., Uddin Md. A.: J. Anal. Appl. Pyrolysis 2004, 72, 27.

9. Kiguchi J., Kamazawa T., Nakai T.: Hydrocarbon Process. 1976, March, 69.

10. Widawi H., Zhang Z. C.: Catal. Today 1996, 30, 99.

11. Widawi H., Wyatt M.: Platinum Met. Rev. 1993, 37,186.

12. Pat. US 4 829 044 (1989).

13. Pat. US 4 305 844 (1981).

14. Pinna R: Catal. Today 1998, 41, 129.

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