Silver-nanoparticles immobilized initiators and co-initiators for free radical polymerization

F. Ścigalski; B. Jędrzejewska; M. Pietrzak; W. Wiśniewski; J. Pączkowski

Published : 2011-04-30

Vol. 56 No. 4 (2011)

Silver-nanoparticles immobilized initiators and co-initiators for free radical polymerization

F. Ścigalski B. Jędrzejewska M. Pietrzak W. Wiśniewski J. Pączkowski

Abstract

The specific properties of silver-nanoparticles immobilized initiator and co-initiators for free radical polymerization have been described. The silver-nanoparticles immobilized mercaptobenzophenone (Bp-MPCs) photoinitiates free radical polymerization in both UV and visible regions. The photoinitiation ability of Bp-MPCs in visible region, e.g. in the region in which benzophenone chromophore does not absorb a light, indicates a possible two-photon action even at low incident light intensity. The co-initiation process caused by silver-nanoparticles immobilized mercaptoamino acids (MA-MPCs) is more efficient in comparison to co-initiation observed for corresponding free mercaptoamino acid. This behavior can be attributed the specific interaction of sulfur electrons with surface plasmon electrons that make an electron transfer from mercaptoamino acid to excited electron acceptor more efficient, or to a high concentration of the electron donor in the ligand shell.

Keywords

nanocząstki srebra ; polimeryzacja wolnorodnikowa ; fotoinicjatory ; merkaptobenzofenony ; merkaptoaminokwasy silver nanoparticles ; free radical polymerization ; photoinitiators ; mercaptobenzophenones ; mercaptoamino acids

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Ścigalski, F., Jędrzejewska, B., Pietrzak, M., Wiśniewski, W., & Pączkowski, J. (2011). Silver-nanoparticles immobilized initiators and co-initiators for free radical polymerization. Polimery, 56(4), 281–288. Retrieved from https://ichp.vot.pl/index.php/p/article/view/917

References

a) Pączkowski J., Neckers D. C.: „Photoinduced Electron Transfer Initiating Systems for Free Radical Polymerization. In Electron Transfer in Chemistry” (Ed. Gould I. R.), Wiley-VCH, New York 2001, vol 5, pp. 516-585. b) Reiser A.: „In Photoreactive Polymers, the Science and Technology of Resists”, Wiley, New York 1989.

2. Gupta S., Gupta N., Neckers D. C.: J. Polym. Sci. Part A: Polym. Chem. 1982, 20, 147.

3. Angiolini L., Caretti D., Carlini C., Lelli N., Rolla P. A.: J. Appl. Polym. Sci. 1993, 48, 1163.

4. Fouassier J. P., Ruhlmann D., Zahouily L., Angiolini L., Carlini C., Lelli N.: Polymer 1992, 33, 3569.

5. Angiolini L., Caretti D., Salatelli E.: Macromol. Chem. Phys. 2001, 201, 2646.

6. Allonas X., Fouassier J. P., Angiolini L., Caretti D.: Helvetica Chimica Acta 2001, 84, 2577.

7. Pączkowska B., Pączkowski J., Neckers D. C.: Polimery 1994, 39, 527.

8. Templeton A. C., Wuelfing W. P., Murray R. W.: Ace. Chem. Res. 2000, 33, 27.

9. Thomas K. G., Kamat P. V.: Ace. Chem. Res. 2003, 36, 888.

10. Goodman C. M., Rotello V. M.: Mini-Rev. Org. Chem. 2004, 1, 103.

11. Novak J. P., Brousseau L. C., Vance F. W., Johnson R. C., Lemon B. I., Hupp J. P., Feldheim D. L.: J. Am. Chem. Soc. 2000, 122, 12 029.

12. MacBeath G., Schreiber S. L.: Science 2000, 289, 1760.

13. Choi I. S., Langer R.: Macromolecules 2001, 34, 5361.

14. Yoon K. R., Lee K.-B., Chi Y. S., Yun W. S., Joo S.-W., Choi L. S.: Adv. Mater. 2003, 15, 2063.

15. Dyer D. J., Feng J., Schmidt R., Wong V. N., Zhao T., Yagci Y: Macromolecules 2004, 37, 7072.

16. Shan J., Nuopponen M., Jiang H., Vitala T., Kauppinen E., Kontturi K., Tenhu H.: Macromolecules 2005, 39, 2918.

17. Neckers D. C., Hassoon S., Klimtchuk E.: J. Photochem. Photobiol. A: Chem. 1996, 95, 33.

18. Polykarpov A. Y, Hassoon S., Neckers D. C.: Macromolecules 1996, 29, 8274.

19. Tanabe T., Torres-Filho A., Neckers D. C.: J. Polym. Sci. Part A: Polym. Chem. 1995, 33, 1691.

20. Murthy S., Bigioni T. P., Wang Z. L., Khoury J. T., Whetten R. L.: Mater. Lett. 1997, 30, 321.

21. Kang S. Y, Kim K.: Langmuir 1998, 14, 226.

22. Roper T. M., Lee T. Y, Guymon A. C., Hoyle C. E.: Macromolecules 2005, 38, 10 109.

23. Roper T. M., Guyman C. A., Hoyle C. E.: Rev. Sci. Instrum. 2005, 76, 054102.

24. Pączkowski J., Krzekotowski J., Stróżecki S.: Pomiary, Automatyka, Kontrola 1978, 26, 8250.

25. Hosteller M. J., Green S. J., Stokes J. J., Murray R. W.: J. Am. Chem. Soc. 1996, 118, 4212.

26. Hosteller M. J., Templeton A. C., Murray R. W.: Langmuir 1999, 15, 3782.

27. Daniel M.-C, Astruc D.: Chem. Rev. 2004, 104, 293.

28. Evanoff D. E., Chumanov G. J.: J. Phys. Chem. B. 2004, 108, 13 957.

29. Jędrzejewska B., Pietrzak M., Ścigalski F., Tomczyk Z., Pączkowski J.: Mater. Lett. 2008, 62, 4260.

30. Stellacci R, Bauer C. A., Meyer-Friedrichsen T., Wenseleers W., Mardeer S. R., Perry J. W.: J. Am. Chem. Soc. 2003, 125, 328.

31. a) Kucybata Z., Pietrzak M., Pączkowski J.: Chem. Mater. 1998,10(11), 3555. b) Kabatc J., Pietrzak M., Pączkowski J.: J. Chem. Soc. Perkin Trans. 2002, 2, 287. c) Jędrzejewska B., Marciniak A., Pączkowski J.: Mater. Chem. Phys. 2008, 111, 400. d) Kabatc J., Jędrzejewska B., Pączkowski J.: J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 6345. e) Kabatc J., Kaczorowska M., Jędrzejewska B., Pączkowski J.: J. Appl. Polym. Sci. 2008, 108, 1636.

32. Kabatc J., Jędrzejewska B., Pączkowski J.: J. Polym. Sci. Part A: Polym. Chem. 2003, 41, 3017.

33. Kabatc J., Jędrzejewska B., Pączkowski J.: J. Appl. Polym. Sci. 2006, 99(1), 207.

34. Zhang S., Li B., Tang L., Wang X., Liu D., Zhou Q.: Polymer 2001, 42, 7575. Received 19 III 2010.

Google Scholar

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

F. Ścigalski polimery@ichp.pl

B. Jędrzejewska

M. Pietrzak

W. Wiśniewski

J. Pączkowski