Crosslinking of styrene-butadiene rubber with redox systems at low temperatures

T. Pingot; M. Pingot; M. Zaborski

Published : 2010-12-30

Vol. 55 No. 11-12 (2010)

Crosslinking of styrene-butadiene rubber with redox systems at low temperatures

T. Pingot M. Pingot M. Zaborski

Abstract

The possibilities of crosslinking styrene butadiene rubber (SBR) at low temperatures with a series of redox systems made up of different types of reducing and oxidizing agents have been explored (Table 1). Transition metal salts were used as reducing agents. A pronounced decrease in the activation energy of the crosslinking process (Fig. 1) was achieved by adopting this method, therefore the crosslinking reaction could be performed at temperatures as low as 80 °C. The influence of the composition of the redox system on rheometrical properties (Table 2), the crosslinking process (Figs. 2 and 3), crosslinking density (Figs. 4-6, Table 3) as well as on mechanical properties was determined. Moreover, the ageing process of unfilled and filled vulcanizates with silicates under UV irradiation was evaluated (Table 4, Figs. 7 and 8). The possibility of crosslinking SBR at low temperatures with the application of systems containing cumene hydroperoxide, in which the reducing agent had been replaced by an ammonium salt - tetrabutylammonium bromide (TBAB) or tetraoctylammonium bromide (TOAB) was also explored.

Keywords

układy redoks ; kauczuk butadienowo-styrenowy ; sieciowanie ; kinetyka ; temperatura procesu ; wulkanizaty ; właściwości użytkowe ; starzenie redox systems ; styrene-butadiene rubber ; crosslinking ; kinetics ; process temperature ; vulcanizates ; application properties ; ageing

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Pingot, T., Pingot, M., & Zaborski, M. (2010). Crosslinking of styrene-butadiene rubber with redox systems at low temperatures. Polimery, 55(11-12), 825–831. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1070

References

Haward R. N.: „Developments in Polymerisation-2”, Applied Science Publishers LTD, London 1979, str. 1-16.

2. Matyjaszewski K., Paris T.: „Handbook of Radical Polymerization”, Wiley-Interscience, Hoboken 2002, str. 117-131.

3. Loganathan K. S.: „Rubber engineering”, Mc-Graw Hill, New York 2000, str. 446, 807-852.

4. Sarac A. S.: Prog. Polym. Sci. 1999, 24, 1149.

5. Misra G. S.: Enc. Polym. Sci. 1985-1989, 8, 61-131.

6. Bicak N., Ozeroglu C.: Eur. Polym. J. 2001, 37, 2393.

7. Chern C. S.: Prog. Polym. Sci. 2006, 31, 443.

8. Lamb D. J., Fellows C. M., Gillbert R. G.: Polymer 2005, 46, 7874.

9. Eisenberg P., Lucas J. C., Williams R. J.: Polimery 1999, 44, 735.

10. Penczek P.: Polimery 1995, 40, 617.

11. Rokicki G.: Polimery 1995, 40, 630.

12. Duliban J.: Polimery 2004, 49, 774.

13. Jellinek H. H. G.: „Degradation and Stabilization of Polymers”, Elsevier Science Publishing Company, New York 1983, str. 337-355.

14. Rozancew E. G., Szolle W. D.: ,”Chemia organiczna wolnych rodników”, Warszawa 1985, str. 28-34.

15. Sikorski R. T.: ,”Podstawy chemii i technologii polimerow”, PWN, Warszawa 1985, str. 83-88.

16. Goodman S. H.: „Handbook of Thermoset Plastics”, Noyes Publication, Westwood 1998, str. 97-166.

17. Flory J. P., J. Rehner Jr.: J. Chem. Phys. 1943, 11, 512.

18. Maksyuta N. V., Suprun V., Opeida L. A., Turovskii N. A.: RMS. J. Org. Chem. 2001, 37, 814.

19. Rado R.: ,”Reakcje polimerów inicjowane przez nadtlenki”, WNT, Warszawa 1974, str. 22.

20. Jones L., Atkins P.: ,”Chemia ogólna”, PWN, Warszawa 2004, str. A14.

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