Badania właściwości elektrochemicznych i spektroelektrochemicznych (UV-Vis, EPR) pochodnych trimeru tiofenu podstawionych grupą fenylowinylową

M. Łapkowski; M. Jadamiec; D. L. Officer; P. Wagner; A. Stolarczyk; K. C. Gordon; W. W. Sułkowski; M. Bartoszek

Published : 2009-03-15

Vol. 54 No. 3 (2009)

Investigations of electrochemical and spectroelectrochemical properties (UV-Vis, EPR) of thiophene trimer derivatives substituted with phenylvinyl groups

M. Łapkowski M. Jadamiec D. L. Officer P. Wagner A. Stolarczyk K. C. Gordon W. W. Sułkowski M. Bartoszek

Abstract

The results of investigations concerning electrochemical properties of two thiophene trimers derivatives substituted with phenylvinyl groups {3'[(E)-2-phenylethenyl]-2,2':5',2''-thiophene (monomer A) and 4,4''-didecyloxy-3'[(E)-2-phenylethenyl]-2,2':5',2''-thiophene (monomer B)} and the products of their oxidation were discussed. Electropolymerizations of A and B monomers were carried out with use of cyclic voltammetry and electrochemical measurements were coupled in-situ with spectroscopic methods (UV-Vis, EPR). It was found that A monomer oxidized to oligomers soluble in dichloromethane (Fig. 1-4 and 7) while monomer B showed ability to form stable conductive polymer layers showing low-energy forbidden band (1.6eV) (Fig. 1, 5, 6 and 8, 9).

Keywords

polimery przewodzące ; tertiofen ; grupa fenylowinylowa ; elektropolimeryzacja ; elektrochemiczne i spektroelektrochemiczne właściwości conductive polymers ; thiophene trimer ; phenylvinyl group ; electropolymerization ; electrochemical and spectroelectrochemical properties

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Łapkowski, M., Jadamiec, M., Officer, D. L., Wagner, P., Stolarczyk, A., Gordon, K. C., Sułkowski, W. W., & Bartoszek, M. (2009). Investigations of electrochemical and spectroelectrochemical properties (UV-Vis, EPR) of thiophene trimer derivatives substituted with phenylvinyl groups. Polimery, 54(3), 209-215. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1192

References

Skotheim T. A., Reynolds J. R.: ,,Handbook of Conducting Polymers'7, t. II, New York 1998.

2. Grandstrom M., Petritsch K., Arias A. C, Lux Av Andersen M. R., Fried R. H.: Nature 1998, 395,257.

3. Sariciftci N. S.: Materials Today 2004,36.

4. Moliton: ,,Molecular and Polymer Optoelectronics: from Concepts to Devices, Springer Series in Optical Sciences'', Springer, New York 2005.

5. Gondek E., Sanetra J., Armatys P., Niziol J., Chacza-trian K., Danel A.: Polimery 2004,49,163.

6. Yang G., Qin Ch., Su Z., Dong S.: THEOCHEM 2005, 726,61.

7. Cutler C. A., Burrel A. K., Officer D. L., Too C. O., Wallance G. G.: Synth. Met. 2002,128,35.

8. Burrel A. K., Chen J., Collis G. E., Grant D. E., Officer D. L., Too C. O., Wallance G. G.: Synth. Met. 2003, 135—136,97.

9. Wagner P., Ballantyne A. M., Jolley K. W., Officer D. L.: Thetrahedron 2006, 62,2190.

10. Gordon K. C., Clarke T. M., Officer D. L., Hall S. B., Collis G. E., Burrel A.K.: Synth. Met. 2003,137,1367.

11. Wagner P., Officer D. L.: Synth. Met. 2005,154,325.

12. Cutler C. A., Burrel A. K., Collis G. E., Dastoor P. C., Officer D. L.: Synth. Met. 2001,123,225.

13. Clarke T. M., Gordon K. C., Officer D. L., Hall S. B., Collis G. E., Burrel A. K.: /. Phis. Chem. 2003, 107, 11505.

14. Sze On Chan H., Choon S.: Prog. Polym. Sci. 1998,23, 1163.

15. Roncali J.: Chem. Rev. 1992, 92, 711.

16. Frere P., Raimundo J. M., Blanchard P., Delaunay J.: /. Org. Chem. 2003, 68, 7254.

17. Wagner P., Partridge A. C., Jolleya K. W., Officer D. L.: Tetrahedron Lett. 2007,48, 6245.

18. Gambhir S., Wagner K., Officer D. L.: Synth. Met. 2005,154,117.

19. Zak J., Lapkowski M., Guillerez S., Bidan G.: Synth. Met. 2005,152,185.

20. Clarke T. M., Gordon K. C., Officer D. L., Grant D. K.: /. Phys. Chem. A. 2005,109,1961.

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M. Łapkowski

M. Jadamiec Malgorzata.Jadamiec@polsl.pl

Affiliation
Politechnika Śląska, Wydział Chemiczny, ul. Marcina Strzody 9, 44-100 Gliwice

D. L. Officer

P. Wagner

A. Stolarczyk

K. C. Gordon

W. W. Sułkowski

M. Bartoszek