Thermomechanical properties and chemical resistance of alkyl methacrylate/N-(4-chlorophenyl)maleimide copolymers

A. Ryttel

Published : 2022-09-17

Vol. 48 No. 10 (2003)

Thermomechanical properties and chemical resistance of alkyl methacrylate/N-(4-chlorophenyl)maleimide copolymers

A. Ryttel

Abstract

The copolymerizations of methyl, ethyl, butyl, pentyl, or octyl methacrylates with N-(4-chlorophenyl)maleimide [N-(4-ClPh)MI] initiated with benzoyl peroxide at the temperature range 60- 110degreesC were carried out. The content of N-(4-ClPh)MI in the initial mixtures of the monomers were 5 or 10 wt. %. N-(4- ClPh)MI was synthesized from maleic anhydride and 4- chloroaniline, in a two-step reaction. Selected properties of resulting copolymers, e.g. thermal stability, chemical resistance, Vicat softening point, T-g and hardness were determined. The influences of N-(4-ClPh)MI content in the copolymers and the length of alkyl group in methacrylates on their properties were discussed.

Keywords

kopolimery ; metakrylany alkilowe ; N-(4--chlorofenylo)maleimid ; stabilność termiczna ; odporność chemiczna ; temperatura zeszklenia ; twardość copolymers ; alkyl methacrylates ; N-(4-chlorophenyl)maleimide ; thermal stability ; chemical resistance ; glass transition temperature ; hardness

Similar Articles

J. Garbarski, M. Fabijański, Properties of high impact polystyrene flame retarded by magnesium hydroxide and modified with triblock copolymer styrene/butadiene/styrene , Polimery: Vol. 50 No. 3 (2005)
D. Sobków, K. Czaja, Influence of accelerated ageing conditions on the process of polyolefines degradation , Polimery: Vol. 48 No. 9 (2003)
A. Shyichuk, G. Tokaryk, A comparison of methods to determination of macromolecule crosslinking yield from gel fraction data - Rapid Communication , Polimery: Vol. 50 No. 3 (2005)
Z. Heen, J. Sajewicz, M. Rajkiewicz, Problem of resorcin elimination from adhesive systems for steel cords , Polimery: Vol. 48 No. 9 (2003)
T. Pokropski, A. Balas, Epoxy resins and polyurethanes — mutual modifying influence. Part II. Interpenetrating polymer networks (IPN) , Polimery: Vol. 48 No. 9 (2003)
W. Brostow, V. M. Castańo, G. Martinez-Barrera, Gamma irradiation effect on polystyrene + SBR blends: morphology and microhardness , Polimery: Vol. 50 No. 9 (2005)
Rasha El-Mekawy, Environmentally hazard and toxic exoskeletons of marine crustaceans wastes in synthesizing N-deacetylated chitin , Polimery: Vol. 67 No. 10 (2022)
Z. Hehn, A. Gawdzik, J. Sajewicz, Effects of butanetetracarboxylic acid and chitosan on the properties of formaldehyde free finish for cotton fabrics , Polimery: Vol. 50 No. 6 (2005)
R. Jeziórska, New higher added value polymeric materials made of fabrics wastes containing poly(ethylene terephthalate) , Polimery: Vol. 50 No. 6 (2005)
B. Osowiecka, J. Zieliński, J. Polaczek, Z. Machowska, Application of waste polycarbonate-furfurol thermolyzates to modification of petroleum bitumens , Polimery: Vol. 47 No. 4 (2002)

<< < 96 97 98 99 100 101 102 103 104 105 > >>

You may also start an advanced similarity search for this article.

Details

Statistics

Authors

Download files

PDF

Zasady cytowania

Ryttel, A. (2022). Thermomechanical properties and chemical resistance of alkyl methacrylate/N-(4-chlorophenyl)maleimide copolymers. Polimery, 48(10), 695–700. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1915

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0