Novel multicomponent functionalized biopolymers with enhanced thermal and dielectric properties

Sanjeeta  Rani; Syed Kashif  Ali; Pawan  Kumar; Kunwar Sugam  Anugrah; Laishram  Saya; Geetu  Gambhir; Drashya  Gautam; Sunita  Hooda; Manisha Verma

doi:10.14314/polimery.2023.7.4

Published : 2023-09-28

Vol. 68 No. 7-8 (2023)

Novel multicomponent functionalized biopolymers with enhanced thermal and dielectric properties

Sanjeeta Rani https://orcid.org/0000-0002-5761-2134 Syed Kashif Ali https://orcid.org/0000-0002-3323-6672 Pawan Kumar https://orcid.org/0009-0001-9464-2404 Kunwar Sugam Anugrah https://orcid.org/0009-0007-2981-0305 Laishram Saya https://orcid.org/0009-0003-7623-2350 Geetu Gambhir https://orcid.org/0000-0002-8995-9714 Drashya Gautam https://orcid.org/0000-0002-3374-0465 Sunita Hooda https://orcid.org/0000-0001-8002-400X Manisha Verma https://orcid.org/0000-0001-9092-2081

DOI: https://doi.org/10.14314/polimery.2023.7.4

Abstract

A new functionalized biopolymer was obtained by adding ethylenediaminetetraacetic acid to chitin and magnetite nanoparticles (Fe₃O₄). Thermogravimetric analysis was performed, and dielectric properties were examined. The obtained biopolymer showed better thermal stability, as evidenced by a higher onset temperature. The activation energy calculated using imaginary impedance data and Nyquist plots was found to be consistent. Moreover, the dielectric permittivity decreased rapidly with increasing frequency. At high frequencies, there was no dependence of dielectric loss on temperature and frequency. The obtained biopolymer can be used in many applications such as microwave devices, deflection yoke, high-frequency capacitors, sensors, etc.

Keywords

biopolimery ; chityna ; nanocząstki ; magnetyt ; właściwości dielektryczne biopolymers ; chitin ; nanoparticles ; magnetite ; dielectric properties

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Rani, S. ., Ali, S. K. ., Kumar, P. ., Anugrah, K. S. ., Saya, L. ., Gambhir, G. ., Gautam, D. ., Hooda, S. ., & Verma, M. (2023). Novel multicomponent functionalized biopolymers with enhanced thermal and dielectric properties. Polimery, 68(7-8), 386-395. https://doi.org/10.14314/polimery.2023.7.4

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Sanjeeta Rani
https://orcid.org/0000-0002-5761-2134

Affiliation
Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi -110019, India

Syed Kashif Ali
https://orcid.org/0000-0002-3323-6672

Affiliation
Department of Chemistry, Faculty of Science, Jazan University, Jazan P.O. Box 82817, Saudi Arabia

Pawan Kumar
https://orcid.org/0009-0001-9464-2404

Affiliation
Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi -110019, India

Kunwar Sugam Anugrah
https://orcid.org/0009-0007-2981-0305

Affiliation
Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi -110019, India

Laishram Saya
https://orcid.org/0009-0003-7623-2350

Affiliation
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi - 110019, India

Geetu Gambhir
https://orcid.org/0000-0002-8995-9714

Affiliation
Advance Chemistry Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi -110019, India

Drashya Gautam
https://orcid.org/0000-0002-3374-0465

Affiliation
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi - 110019, India

Sunita Hooda
https://orcid.org/0000-0001-8002-400X

Affiliation
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi - 110019, India

Manisha Verma manishaverma@andc.du.ac.in
https://orcid.org/0000-0001-9092-2081

Affiliation
Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi -110019, India