Polimeryzacja koordynacyjna alkenylosilseskwioksanów i ich kopolimeryzacja z olefinami lub styrenem

P. Groch; K. Dziubek; K. Czaja

doi:10.14314/polimery.2015.289

Published : 2015-05-30

Vol. 60 No. 5 (2015)

Coordination polymerization of alkenylsilsesquioxanes and their copolymerization with olefins or styrene

P. Groch K. Dziubek K. Czaja

DOI: https://doi.org/10.14314/polimery.2015.289

Abstract

The paper is acontinuation of literature review on the coordination polymerization of silsesquioxanes (POSS) containing apolymerizable double bond and their copolymerization with alkenes and styrene. In both these cases, an efficient (co)polymerization can be achieved by using metallocene catalysts activated with methylalumoxane (MAO). The incorporation of POSS comonomer to the polymeric material positively affects the properties of the obtained products. They show improved heat resistance and higher mechanical strength than their non-modified counterparts.

Keywords

poliedryczne oligomeryczne silseskwioksany (POSS) ; katalizatory metalocenowe ; kopolimeryzacja koordynacyjna ; właściwości mechaniczne ; właściwości termiczne polyhedral oligomeric silsesquioxanes (POSS) ; metallocene catalysts ; coordination (co)polymerization ; mechanical properties ; thermal properties

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Zasady cytowania

Groch, P., Dziubek, K., & Czaja, K. (2015). Coordination polymerization of alkenylsilsesquioxanes and their copolymerization with olefins or styrene. Polimery, 60(5), 289-297. https://doi.org/10.14314/polimery.2015.289

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P. Groch polimery@ichp.pl

Affiliation
Uniwersytet Opolski,Wydział Chemii, Katedra Technologii Chemicznej i Chemii Polimerów, ul. Oleska 48, 45-052 Opole

K. Dziubek

Affiliation
Uniwersytet Opolski,Wydział Chemii, Katedra Technologii Chemicznej i Chemii Polimerów, ul. Oleska 48, 45-052 Opole

K. Czaja

Affiliation
Uniwersytet Opolski,Wydział Chemii, Katedra Technologii Chemicznej i Chemii Polimerów, ul. Oleska 48, 45-052 Opole