Crystallization kinetics of polycaprolactone in nanocomposites

M. Mucha; M. Tylman; J. Mucha

doi:10.14314/polimery.2015.686

Published : 2015-12-30

Vol. 60 No. 11-12 (2015)

Crystallization kinetics of polycaprolactone in nanocomposites

M. Mucha M. Tylman J. Mucha

DOI: https://doi.org/10.14314/polimery.2015.686

Abstract

The paper presents research results on the crystallization kinetics of polycaprolactone (PCL) with micro- and nano-additives such as talc (nucleation agent) and nanosilver (antibacterial agent). The process of isothermal crystallization was studied in a narrow temperature range 38.5—41.5 °C using Differential Scanning Calorimetry (DSC) and Thermooptical Analysis (TOA) methods. The kinetics of the process are described using the Avrami model. The parameters n and log K of the equation were calculated. Changes in the half time of crystallization, degree of crystallinity and melting temperature of the polymer under the influence of the fillers and the conditions of crystallization were analyzed.

Keywords

crystallization ; polycaprolactone ; nanosilver ; talc ; nanocomposites krystalizacja ; polikaprolakton ; nanosrebro ; talk ; nanokompozyty

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Mucha, M., Tylman, M., & Mucha, J. (2015). Crystallization kinetics of polycaprolactone in nanocomposites. Polimery, 60(11-12), 686–692. https://doi.org/10.14314/polimery.2015.686

References

Simioni A.R., Vaccari C., Re M.I., Tedesco A.C.: Journal of Materials Science 2008, 43, 580. http://dx.doi.org/10.1007/s10853-007-1652-4

[2] Kweon H.Y., Kyong Y. et.al.: Biomaterials 2003, 24, 802.

[3] Park S.A., Lee S.H., Kim W.D.: Bioprocess and Biosystem Engineering 2011, 34, 505. http://dx.doi.org/10.1007/s00449-010-0499-2

[4] Zhuravlev E., Schmelzer W.P., Wunderlich B., Schick Ch.: Polymer 2011, 52, 1983. http://dx.doi.org/10.1016/j.polymer.2011.03.013

[5] Lorenzo A.T., Arnal M.L., Albuerne J., Müller A.J.: Polymer Testing 2007, 26, 222. http://dx.doi.org/10.1016/j.polymertesting.2006.10.005

[6] Acierno S., Iannace S., Grizzuti N.: Rheologica Acta 2006, 45, 387. http://dx.doi.org/10.1007/s00397-005-0054-2

[7] Tang J.H., Qing L.Q., Ying Z.Y.: Advanced Materials Research 2011, 332, 1235.

[8] Sumitha M.S., Shalumon K.T., Sreeja V.N. et al.: Journal of Macromolecular Science, Part A: Pure and Applied Chemistry 2012, 49, 131.

[9] Kyung K.J., Il K.K., Sung H.D.: Materials Letters 2014, 132, 312.

[10] Maio E.D., Iannace S., Sorrentino L., Nicolais L.: Polymer 2004, 45, 8893. http://dx.doi.org/10.1016/j.polymer.2004.10.037

[11] Guo Q., Groeninckx G.: Polymer 2001, 42, 8647. http://dx.doi.org/10.1016/S0032-3861(01)00348-2

[12] Alp B., Cesur S., Balkose D.: “Crystallization control of polycaprolactone (PCL) with inorganic and organic additives”, Conference materials: 18th International Symposium on Industrial Crystallization, Zurich 2011.

[13] Zhu G., Xu Q., Qin R., Liang G.: Radiation Physics and Chemistry 2005, 74, 42. http://dx.doi.org/10.1016/j.radphyschem.2004.11.006

[14] Congde Q., Shichun J., Xiangling J., Lijia A., Bingzheng J.: Frontiers of Chemistry in China 2007, 2, 343. http://dx.doi.org/10.1007/s11458-007-0065-x

[15] Avrami M.: Journal of Chemistry and Physics 1939, 7, 1103. http://dx.doi.org/10.1063/1.1750380

[16] Wunderlich B.: “Macromolecular physics, crystal nucleation, growth, annealing”, Academic Press, New York 1976, vol. 2.

[17] Price F.P., Thornton J.M.: Journal of Applied Physics 1973, 44, 4312. http://dx.doi.org/10.1063/1.1661956

[18] Peterlin A.: Journal of Applied Physics 1964, 35, 75. http://dx.doi.org/10.1063/1.1713102

[19] Skoglund P., Fransson A.: Journal of Applied Polymer Science 1996, 61, 2455.

[20] Gorrasi G., Tortora M., Vittoria V. et al.: Polymer 2003, 44, 2271. http://dx.doi.org/10.1016/S0032-3861(03)00108-3

Google Scholar

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

M. Mucha michal.tylman@p.lodz.pl

Affiliation
Technical University of Łódź, Faculty of Process and Environmental Engineering, ul. Wólczańska 213, 90-924 Lodz, Poland

M. Tylman

Affiliation
Technical University of Łódź, Faculty of Process and Environmental Engineering, ul. Wólczańska 213, 90-924 Lodz, Poland

J. Mucha

Affiliation
Technical University of Łódź, Faculty of Civil Engineering, Architecture and Environmental Engineering, al. Politechniki 6, 90-924 Lodz, Poland