Synteza kopolimerów poli(uretanowo-metakrylowych) z zastosowaniem makroinicjatora tetrafenyloetanouretanowego metodą polimeryzacji kontrolowanej ARGET ATRP

P. Król; P. Chmielarz

doi:10.14314/polimery.2014.279

Published : 2014-04-30

Vol. 59 No. 4 (2014)

Synthesis of poly(urethane-methacrylate) copolymers using tetraphenylethane-urethane macroinitiator by ARGET ATRP controlled polymerization method

P. Król P. Chmielarz

DOI: https://doi.org/10.14314/polimery.2014.279

Abstract

Poly(methyl methacrylate)-b-polyurethane-b-poly(methyl methacrylate) tri-block copolymers were synthesized for the first time using ARGET ATRP method. A specially prepared for this purpose tetraphenylethane-urethane macroinitiator (TPE-PUR-TPE) was used as a transitional product reacting with methyl methacrylate (MMA) in the presence of CuBr2 or CuCl2 catalyst and N,N,N',N”,N”-pentamethyldiethylenetriamine (PMDETA) or 2,2'-bipyridine (Bpy) as a complexing agent. It was found that both the molecular weight of the resulting copolymer versus MMA conversion and the value of ln([M]0/[M]) as a function of polymerization time increase linearly. High coefficients of linear correlation for the studied relationships indicate that the formation of tri-block copolymers takes place according to the mechanism of atom transfer radical polymerization. The results of FT-IR, 1H and 13C NMR spectral analyses as well as DSC and TGA thermal studies confirm the expected chemical structure of the synthesized macroinitiator and poly(urethane-methacrylate) copolymers produced with its involvement. Additionaly, the studies of surface properties (roughness, contact angle and SFE) of polymer films prepared from these copolymers indicate, based on the observed increase of hydrophobicity, the presence of block segments derived from PMMA.

Keywords

kopolimery poli(uretanowo-metakrylowe) ; mechanizm polimeryzacji ARGET ATRP ; struktura chemiczna ; swobodna energia powierzchniowa ; morfologia powierzchni ; właściwości termiczne poly(urethane-methacrylate) copolymers ; ARGET ATRP polymerization mechanism ; chemical structure ; free surface energy ; surface morphology ; thermal properties

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Król, P., & Chmielarz, P. (2014). Synthesis of poly(urethane-methacrylate) copolymers using tetraphenylethane-urethane macroinitiator by ARGET ATRP controlled polymerization method. Polimery, 59(4), 279-292. https://doi.org/10.14314/polimery.2014.279

References

Kwak Y., Matyjaszewski K.: Polym. Int. 2009, 58, 242,
Crossref

[2] Mueller L., Jakubowski W., Tang W., Matyjaszewski K.: Macromolecules 2007, 40, 6464,
Crossref

[3] di Lena F., Matyjaszewski K.: Prog. Polym. Sci. 2010, 35, 959,
Crossref

[4] Chan N., Cunningham M.F., Hutchinson R.A.: Macromol. Chem. Phys. 2008, 209, 1797,
Crossref

[5] Hu Z., Shen X., Qiu H., Lai G., Wu J., Li W.: Eur. Polym. J. 2009, 45, 2313,
Crossref

[6] Casolari R., Felluga F., Frenna V., Ghelfi F., Pagnoni U.M., Parsons A.F., Spinelli D.: Tetrahedron 2011, 67, 408,
Crossref

[7] Gnanou Y., Hizal G.: J. Polym. Sci., Part A 2004, 42, 351,
Crossref

[8] Nicolay R.,Kwak Y., Matyjaszewski K.: Angew. Chem. 2010, 122, 551,
Crossref

[9] Okelo G.O., He L.: Biosen. Bioel. 2007, 23, 588,
Crossref

[10] Matyjaszewski K., Coca S., Gaynor S.G., Wei M., Woodworth B.E.: Macromolecules 1998, 31, 5967,
Crossref

[11] Dong H., Matyjaszewski K.: Macromolecules 2008, 41, 6868,
Crossref

[12] Matyjaszewski K., Dong H., Jakubowski W., Pietrasik J., Kusumo A.: Langmuir 2007, 23, 4528,
Crossref

[13] Tharanikkarasu K., Verma H., Jang W., Lee S.K., Seo J., Baek S., Han H.: J. Appl. Polym. Sci. 2008, 108, 1538,
Crossref

[14] Verma H., Kannan T.: Polym. J. 2008, 40, 867,
Crossref

[15] Verma H, Tharanikkarasu K.: J. Macromol. Sci., Part A2010, 47, 407,
Crossref

[16] Verma H., Tharanikkarasu K.: Express Polym. Lett. 2008, 8, 579,
Crossref

[17] Kim B.K., Lee J.S., Lee M.Ch., Yoon K.S.: J. Appl. Polym. Sci. 2003, 88, 1971,
Crossref

[18] Zgłosz. Pat. USA 20 060 167 177 (2006).

[19] Baek S.H., Kim B.S., Kim B.K.: Prog. Org. Coat. 2004, 49, 353,
Crossref

[20] Sharifpoor S., Labow R., Santerre S.P.J.: Biomacromolecules 2009, 10, 2729,
Crossref

[21] Król P., Chmielarz P.: Polimery 2011, 56, 530.

[22] Tharanikkarasu K., Radhakrishnan G.: J. Macromol. Sci., Part A 1996, 33, 417,
Crossref 10601329608010868

[23] Stagg F.E.: Analyst 1946, 71, 557,
Crossref

[24] Król P., Chmielarz P.: Express Polym. Lett. 2013, 7, 249,
Crossref

[25] Król P., Król B., Chmielarz P., Wojturska J.: Polimery 2013, 58, 17,
Crossref

[26] Król B., Król P., Pikus S., Chmielarz P., Skrzypiec K.: Coll. Polym. Sci. 2010, 288, 1255,
Crossref

[27] Król P., Pilch-Pitera B.: Polymer 2003, 44, 5075,
Crossref

[28] Lapprand A., Boisson F., Delolme F., Mechin F., Pascault J.P.: Degrad. Stab. 2005, 90, 363,
Crossref

[29] Król P., Chmielarz P.: „,Modern Polymeric Materials for Environmental Applications”, WNT TEZA, Kraków 2010, str. 169—174.

[30] Nayak S., Verma H., Tharanikkarasu K.: Colloid. Polym. Sci. 2010, 288, 181,
Crossref

[31] Hatada K., Kitayama T., Fujimoto N., Nishiura T.: J. Macromol. Sci., Part A 1993, 30, 645,
Crossref

[32] Król P., Król B.: Polimery 2012, 57, 799

Google Scholar

Altmetric indicators

Citing articles via

CITEDBY SCOPUS

Statistics

Total abstract views : 71

PDF Downloads : 65

P. Król pkrol@prz.edu.pl

Affiliation
Politechnika Rzeszowska, Wydział Chemiczny, Al. Powstańców Warszawy 6, 35-959 Rzeszów

P. Chmielarz

Affiliation
Politechnika Rzeszowska, Wydział Chemiczny, Al. Powstańców Warszawy 6, 35-959 Rzeszów