Thermal and fire retardant properties of polyurea

T. Mariappan; C. A. Wilkie

Published : 2013-05-30

Vol. 58 No. 5 (2013)

Thermal and fire retardant properties of polyurea

T. Mariappan C. A. Wilkie

Abstract

The thermal and fire retardant properties of polyurea, formed by the polyaddition reaction of a modified diisocyanate with an oligomeric diamine, have been studied using thermogravimetric analysis and cone calorimetry as the principal tools. Approximately forty different conventional fire retardant additives including halogens (chlorine and bromine), phosphorus (nearly all oxidation states), mineral fillers, melamine compounds and intumescent additives were used at constant loading of 15 wt. % for all samples (except mineral fillers, 30 wt. %) and evaluated in polyurea. The thermal properties (onset, maximum degradation temperature and char residue) of filled polyurea samples are compared with the control sample. The fire retarded polyurea samples have been screened on the basis of the percentage reduction of peak heat release rate and smoke evolution.

Keywords

polimocznik ; dodatki opóźniające palenie ; właściwości termiczne ; uniepalniacze ; kalorymetria stożkowa polyurea ; fire retardant additives ; thermal properties ; fire retardancy ; cone calorimetry

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Mariappan, T., & Wilkie, C. A. (2013). Thermal and fire retardant properties of polyurea. Polimery, 58(5), 371–384. Retrieved from https://ichp.vot.pl/index.php/p/article/view/743

References

„Polyurea Elastomers”, Technical Information, Hercules, Bahnhofstr, UID Nr. ATU, Villach.

2. Kumar A.: „New Generation Coatings” presentation, VIP Polyurea, Munich, Germany.

3. www.futuracoatings.com/articles/polyurea.html

4. Costache M. C., Kanugh E. M., Wilkie C. A., Sorathia U.: J. Fire Sci. 2006, 24, 433.

5. Awad W. H., Wilkie C. A.: Polymer 2010, 51, 2277.

6. Giraud S., Bourbigot S., Rochery M., Vroman I., Tighzert L., Delobel R., Poutch F.: Polym. Degrad. Stab. 2005, 88, 106.

7. Awad W. H., Nyambo C., Kim S., Dinan R. J., Fisher J. W., Wilkie C. A.: ACS Symposium Series (Eds.Wilkie C. A., Morgan A. B., Nelson G. L.) 2009, 1013, 102.

8. Proceedings of the conference on recent advances in flame retardancy of polymeric materials 2005, 16, 83.

9. Thirumal M., Khastgir D., Singha N. K., Manjunath B. S., Naik Y. P.: J. Appl. Polym. Sci. 2008, 110, 2586.

10. Shi S., Li Z.-M., Xie B.-H.,Wang J.-H., Tian C.-R., Yang M.-Y.: Polym. Int. 2006, 55, 862.

Google Scholar

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0