Synteza reaktywnych żywic siloksanowo-silseskwioksanowych

M. Szołyga; M. Dutkiewicz; B. Marciniec; H. Maciejewski

Published : 2013-10-30

Vol. 58 No. 10 (2013)

Synthesis of reactive siloxane-silsesquioxane resins

M. Szołyga M. Dutkiewicz B. Marciniec H. Maciejewski

Abstract

A series of siloxane-silsesquioxane resins with POSS Q8 structures as network nodes containing reactive SiH groups in the siloxane bridges between silsesquioxane (POSS) molecules were prepared in a hydrolytic condensation process. The effect of reactant molar ratios (POSS/dichloromethylsilane) on the structure of synthesized product was investigated. Attempts were made to carry out the addition reaction of SiH groups with multiple bonds of olefins in the process of hydrosilylation of allyl alcohol. As a result, the resins containing Q8 POSS units and reactive functional groups capable to interact chemically with organic polymers, were obtained. This type of material can be a cheaper but still valuable alternative for the typical POSS compounds.

Keywords

żywice siloksanowe ; kondensacja hydrolityczna ; hydrosililowanie siloxane resins ; hydrolytic condensation ; hydrosilylation

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Szołyga, M., Dutkiewicz, M., Marciniec, B., & Maciejewski, H. (2013). Synthesis of reactive siloxane-silsesquioxane resins. Polimery, 58(10), 766–771. Retrieved from https://ichp.vot.pl/index.php/p/article/view/784

References

Choi J., Kim S., Laine R.: Macromolecules 2004, 37, 99.

2. Lin H., Wu S., Huang P., Huang C.: Macromol. Rapid Commun. 2008, 27, 1550.

3. Yu J., Qiu Z.: ACS Appl. Mater. Interfaces 2011, 3, 890.

4. Wang X., ErvithayasupornV., Zhang Y., Kawakami Y.: Chem. Commun. 2011, 1282.

5. Tanaka K., Inafuku K., Nakab K., Chujo Y.: Org. Biomol. Chem. 2008, 6, 3899.

6. Fabritz S., Hörner S., Könning D., Empting M.: Org. Biomol. Chem. 2012, 10, 6287.

7. Duchateau R.: Chem. Rev. 2002, 102, 3525.

8. Ventura M., Mosquera M. E. G., Cuenca T., Royo B.: Inorg. Chem. 2012, 51, 6345.

9. Cho H. J., Hwang D. H., Lee J. I., Jung Y. K.: Chem. Mater. 2006, 18, 3780.

10. Ervithayasuporn V., Abe J., Wang X., Matsushima T.: Tetrahedron 2010, 66, 9348.

11. Yang X. H., Giovenzana T., Feild B., Jabbour G. E.: J. Mater. Chem. 2012, 22, 12689.

12. Baney R. H., Itoh M., Sakakibara A., Suzuki T.: Chem. Rev. 1995, 95, 1409.

13. Maciejewski H., Dutkiewicz M., Byczyński £., Marciniec B.: Polimery 2012, 57, 535.

14. Lichtenhan J. D., Vu N. Q., Carter J. A.: Macromolecules 1993, 26, 2141.

15. Liu Y. R., Huang Y. D., Liu L.: Compos. Sci. Technol. 2007, 67, 2864.

16. Gunji T., Shioda T., Tsuchihira K., Seki H.: Appl. Organometal. Chem. 2010, 24, 545.

17. Handke M., Kowalewska A.: Spectrochim. Acta Part A 2011, 79, 749.

18. Seino M., Hayakawa T., Ishida Y., Kakimoto M.: Macromolecules 2006, 39, 8892.

19. Pan G., Mark J. E., Schaefer D. W.: J. Polym. Sci.: Part B: Polym. Phys. 2003, 41, 3314.

20. Mantz R. A., Jones P. F., Chaffee K. P., Lichtenhan J. D.: Chem. Mater. 1996, 8, 1250.

21. Ryu H. S., Kim D. G., Lee J. C.: Polymer 2010, 51, 2296.

22. Zgł. Pat. PL 393 092 (2010).

23. Hosegawa I., Nakane Y., Takayama T.: Appl. Organometal. Chem. 1999, 13, 273.

24. Zgł. Pat. P 403 681 (2013).

25. Filho N. L. D., de Aquino H. A., Pires G., Caetano L.: J. Braz. Chem. Soc. 2006, 17, 533.

26. Marciniec B., Maciejewski H., Pietraszuk C., Pawluś P.: „Hydrosilylation — A Comprehensive Review on Recent Advances”, Springer, Londyn 2009.

27. Sing K. S. W., Everett D. H., Haul R. A. W., Moscou L., Pierotti R. A., Rouquérol J., Siemieniewska T.: Pure Appl. Chem. 1985, 57, 603.

28. de Boer J. H.: „The Structure and Properties of Porous Materials”, Butterworth, Londyn 1958.

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M. Szołyga polimery@ichp.pl

Affiliation
Uniwersytet im. A. Mickiewicza w Poznaniu, Wydział Chemii, ul. Umultowska 89b, 61-614 Poznań

M. Dutkiewicz

Affiliation
Uniwersytet im. A. Mickiewicza w Poznaniu, Centrum Zaawansowanych Technologii, ul. Grunwaldzka 6, 60-780 Poznań

B. Marciniec

Affiliation
Uniwersytet im. A. Mickiewicza w Poznaniu, Wydział Chemii, ul. Umultowska 89b, 61-614 Poznań

H. Maciejewski

Affiliation
Uniwersytet im. A. Mickiewicza w Poznaniu, Wydział Chemii, ul. Umultowska 89b, 61-614 Poznań