Syntezy silseskwioksanów z różnymi podstawnikami organicznymi

P. Rościszewski; R. Kazimierczuk; J. Sołtysiak

Published : 2022-08-30

Vol. 51 No. 1 (2006)

Syntheses of silsesquioxanes with various organic substituents

P. Rościszewski R. Kazimierczuk J. Sołtysiak

Abstract

Easy feasible and effective methods of the synthesis of silsesquioxanes [equations (1) - (6)] were elaborated. Twelve types of these products with various organic substituents: the same (Table 1 and 3) or different ones (Table 2 and 3) at silicon atom were obtained. Alkyl, phenyl, vinyl or carbofunctional groups act as substituents. Silsesquioxanes obtained were characterized using the following methods: FT-IR (Fig. 2), 1H NMR (Fig. 3), 29Si NMR, gel permeation chromatography, mass spectrometry (Fig. 4) and scanning electron microscopy (Fig. 5). Molecular weights of liquid silsesquioxanes (soluble in organic solvents) were usually in the range 500-1500 g/mol. Some samples of poly(methyl silsesquioxanes) consisted of spherical particles of dimensions 50-150 nm. It has been found from the results of structural investigations of the products that the structures of closed cage type - mainly T8 (Fig. 1) are formed.

Keywords

poli(alkilo, winylo, fenylo)silseskwioksany ; podstawniki karbofunkcyjne ; synteza ; struktura poly[(alkyl, vinyl, phenyl) silsesquioxanes] ; carbofunctional substituents ; synthesis ; structure

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Rościszewski, P., Kazimierczuk, R., & Sołtysiak, J. (2022). Syntheses of silsesquioxanes with various organic substituents. Polimery, 51(1), 3-11. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1493

References

Scott D. W.: J. Am. Chem. Soc. 1946, 68, 356.

2. Noda I., Isikawa M., Yamawaki M.: Inorg. Chim. Acta 1997/263,149.

3. Lee L., Chen W. H, Lin W. Ch.: J.. Pol. Sci./A 2002, 40, 1560.

4. Brown J. F., Vogt L. H., Prescott P. I.: J. Am. Chem. Soc. 1960, 86,1120.

5. Baney R. H., Itoh M., Saka Kibara A., Suzuki T.:Chem.Rev. 1995, 95,1409.

6. Leśniak E.: Polimery 2001, 46, 516 i 582.

7. Shea K. J., Loy D. A., Webster O.: J. Am. Chem. Soc, 1992,114, 6700.

8. Loy D. A., Shea K. J.: Chem. Rev. 1995, 95,1431.

9. Sellinger A., Laine R. M.: Macromolecules 1996, 29, 2327.

10. Provatas A., Luft M., Mu J. C., White A. H., Matisons J. G., Skelton B. W.: J. Organometal. Chem. 1998, 565, 159.

11. Pyun J., Matyjaszewski K.: Macromolecules 2000, 33, 217.

12. Murfee K. J., Thoms T. P. S., Greaves J.: Inorg. Chem, 2000, 39, 5209.

13. Feher F. J., Weller K. J.: Organometallics 1990, 9, 2638.

14. Feher F. J., Weller K. J.: J. Am. Chem. Soc. 1991, 113, 3618.

15. Feher F. J., Budzikowski T. A., Rahimian K.: J. Am. Chem. Soc. 1992,114/ 3859.

16. Moher P. T., Jeon H. C., Uribe A. R.: Macromolecules 1999,32,1194.

17. Xie P., Guo J. S., Dać D. R., Jin S. Z., Liu D. S.: Poi. Adv. Teclm.1995,7,98.

18. Cerveau G., Chappelet S., Corriu J. P: J. Mater. Chem. 2003,13,2885.

19. Choi J., Harcup J., Yee A. F., Zhu Q.: J. Am. Chem. Soc. 2001,123,11420.

20. Yasuda N., Yamamoto S., Wada Y.: Chem. Letters 2001,1189.

21. Barton T. J., Buli L. M., Klemperer W. G., Loy D. A.: Chem. Mater. 1999,11,2633.

22. Liu W. Ch, Yu Y, Chen W. Ch.: J. Appl. Poi. Sci. 2004, 91,2653.

23. Yoon D. Y: Mat. Res. Soc. Symp. Proc. 2003, 766 (CA 2004,140,128901).

24. Fasce D. R, Wiliams M. J., Machin R, Pascault J. R, Llauro M. E, Petiaud R.: Macromolecules 1999, 32, 4757.

25. Hu L., Sun Y, Zhao S., Liu Z.: Pol. Prep. 2002, 43, 1114.

26. Rościszewski R: Wydawnictwa UAM, Seria Chemia 1985, nr 47,123.

27. Rościszewski R, Strojny T., Zielecka-Szabłowska M., Jagielska E., Iwańska S., Wojtyńska E., Wiecheć L., Brzeziński J.: Polimery 1982, 27,123.

28. Rościszewski R: Plast. Kautsch. 1985, 32,434.

29. Rościszewski R, Kazimierczuk R., Sołtysiak J.: Materiały Ogólnopolskiego Sympozjum Związków Krzemoorganicznych, Dymaczewo 2003, str. 45.

Google Scholar

Citing articles via

Statistics

Total abstract views : 35

PDF Downloads : 21

P. Rościszewski polimery@ichp.pl

Affiliation
Instytut Chemii Przemysłowej im. prof. I. Mościckiego, ul. Rydygiera 8, 01-793 Warszawa

R. Kazimierczuk

J. Sołtysiak