Published : 2022-09-01

Stereocontrolled polymerization of chiral heterocydic monomers

Abstract

A review with 80 references deals with stereoselective (race-mate-forming chirogenic) and stereoelective (asymmetric enantiomer-differentiating) ring-opening polymerizations of chiral oxiranes, thiiranes, lactones, dilactides, and N-carboxyanhydrides of alpha-aminoacids. These enantiocontrolled polymerizations are analyzed in terms of the chain-end control or site control mechanisms (CEM or SCM, respectively). Possibility of formation of highly ordered structures by the resulting izotactic and optically active macromolecules is also discussed.


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Duda, A. (2022). Stereocontrolled polymerization of chiral heterocydic monomers. Polimery, 49(7-8), 469-478. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1773