Solid-state polycondensation (SSP) as a method to obtain high molecular weight polymers. Part II. Synthesis of polylactide and polyglycolide via SSP

I. Steinborn-Rogulska; G. Rokicki

doi:10.14314/polimery.2013.085

Published : 2013-02-28

Vol. 58 No. 2 (2013)

Solid-state polycondensation (SSP) as a method to obtain high molecular weight polymers. Part II. Synthesis of polylactide and polyglycolide via SSP

I. Steinborn-Rogulska G. Rokicki

DOI: https://doi.org/10.14314/polimery.2013.085

Abstract

Solid-state polycondensation (SSP) is a competitive method of semicrystalline polymers synthesis to conventional melt polycondensation process. The molecular weight of polymers obtained according to this method is exceptionally high and the process can be carried out under milder conditions than those of the melt state. In this method the side reactions are suppressed, especially those leading to the polymer degradation. In this paper, which is a continuation of our previous publication, application of the SSP method to obtain high molecular weight poly(lactic acid) (PLA) and poly(glycolic acid) (PGA) — polymers of high importance for medicine and environmental protection — is presented and discussed. The two-phase model according to which polycondensation proceeds in the amorphous regions, and the apparatus usually used in this process are also described.

Keywords

polikondensacja w stanie stałym ; polilaktyd ; poliglikolid ; model dwufazowy solid-state polycondensation ; polylactide ; polyglycolide ; two-phase model

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Steinborn-Rogulska, I., & Rokicki, G. (2013). Solid-state polycondensation (SSP) as a method to obtain high molecular weight polymers. Part II. Synthesis of polylactide and polyglycolide via SSP. Polimery, 58(2), 85-92. https://doi.org/10.14314/polimery.2013.085

References

Maharana T., Mohanty B., Negi Y. S.: Prog. Polym. Sci. 2009, 34, 99.

2. Hartmann M. H.: „Biopolymers from Renewable Resources” (Ed. Kaplan D. L.), Springer-Verlag, 1st edition, Heidelberg 1998, pp. 367—411.

3. Sodergard A., Stolt M.: Prog. Polym. Sci. 1994, 27, 1123.

4. Pat US 5 440 008 (1995).

5. Moon S. I., Lee C.W., Miyamoto M., Kimura Y.: J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 1673.

6. Jamshidi K., Hyon S.-H., Ikada Z.: Polymer 1988, 29, 2229.

7. Papaspyrides C. D., Vouyiouka S. N.: „Fundamentals of Solid-state Polymerization” in „Solid-state Polymerization” (Eds. Papaspyrides C. D., Vouyiouka S. N.), John Wiley & Sons, Hoboken, Jersey 2009, pp. 1—30.

8. Vouyiouka S. N., Karakatsani E. K., Papaspyrides C. D.: Prog. Polym. Sci. 2005, 30, 10.

9. Buxbaum L. H.: J. Appl. Polym. Sci. 1979, 35, 59.

10. Chuah H. H.: „Synthesis, properties and applications of poly( trimethylene terephthalate” in „Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters” (Eds. Scheirs J., Long T. E.), Wiley, Chichester, UK 2003, pp. 361—397.

11. Pat. WO 97/025 364 (1997).

12. Duh B.: J. Appl. Polym. Sci. 2007, 103, 1075.

13. Sun Y.-M., Shieh J.-Y.: J. Appl. Polym. Sci. 2010, 81, 2055.

14. Mallon F. K., Ray W. H.: J. Appl. Polym. Sci. 1998, 69, 1233.

15. Zimmerman J.: J. Polym. Sci., Polym. Lett. Ed. 1964, 2, 955.

16. Zimmerman J., Kohan M. I.: J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 2565.

17. Gostoli C., Pilati F., Sarti G. C., Di Giacomo B.: J. Appl. Polym. Sci. 1984, 29, 2873.

18. Meyer K.: Angew. Makromol. Chem. 1973, 34, 165.

19. Drumright R. E., Gruber P. R., Henton D. E.: Adv. Mater. 2000, 12, 1841.

20. Qian G., Zhou X.-G., Zhu L.-B., Yuan W.-K.: J. Polym. Eng. 2003, 23, 413.

21. ZhangW.-X.,Wang Y.-Z.: Chinese J. Polym. Sci. 2008, 26, 425.

22. Moon S.-I., Lee C.-W., Taniguchi I., Miyamoto M., Kimura Y.: Polymer 2001, 42, 5059.

23. Moon S.-I., Taniguchi I., Miyamoto M., Kimura Y., Lee C.-W.: High Perform. Polym. 2001, 13, 189.

24. Fukushima T., Sumihiro Y., Koyanagi K., Hashimoto N., Kimura Y., Sakai T.: Int. Polym. Proc. 2004, 4, 380.

25. Xu H., Luo M., Yu M., Teng C., Xie S.: J. Macromol. Sci., Part B: Phys. 2006, 45, 681.

26. Fukushima K., Kimura Y.: J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 3714.

27. Fukushima K., Furuhashi Y., Sogo K., Miura S., Kimura Y.: Macromol. Biosci. 2005, 5, 21.

28. Essawy H. A., Helaly F. M., Shabana M. A.: J. Elastom. Plast. 2007, 39, 303.

29. Kativar V., Nanavati H.: Polym. Comp. 2011, 32, 497.

30. Shinno K., Masatoshi M., Kimura Y.: Macromolecules 1997, 30, 6438.

31. Moon S.-I., Deguchi K., Miyamoto M., Kimura Y.: Polym. Int. 2004, 53, 254.

32. Takahashi K., Taniguchi I., Miyamoto M., Kimura Y.: Polymer 2000, 41, 8725.

33. Schwarz K., Epple M.: Macromol. Chem. Phys. 1999, 200, 2221.

34. Pat. US 7 098 300 (2006).

35. Kim T. Y., Lofgren E. A., Jabarin S. A.: J. Appl. Polym. Sci. 2003, 89, 197.

36. Almonacil C., Desai P., Abhiraman A.: Macromolecules 2001, 34, 4186.

37. Gaymans R., Venkatraman V., Schuijer J.: J. Polym. Sci., Polym. Chem. Ed. 1984, 22, 1373.

38. Pat. US 3 821 171 (1974).

39. Roerdink E., Warnier J.: Polymer 1986, 26, 1582.

40. Pat. US 3 476 711 (1969).

41. Huang B., Walsch J. J.: Polymer 1998, 39, 6991.

42. Gaymans R., Amirtharaj J., Kamp H.: J. Appl. Polym. Sci. 1982, 27, 2513.

43. Griskey R., Lee B.: J. Appl. Polym. Sci. 1966, 10, 105.

44. Pat. Jap. 4 933 23 (1992).

45. Pat. US 5 461 141 (1995).

46. Li L., Huang N.-X., Liu Z.-H., Tang Z.-L., YungW.-S.: Polym. Adv. Technol. 2000, 11, 242.

47. Agrawal A. K., Mhaisgawali V. T.: J. Appl. Polym. Sci. 2006, 102, 5113.

Google Scholar

Altmetric indicators

Citing articles via

CITEDBY SCOPUS

Statistics

Total abstract views : 226

PDF Downloads : 520