Influence of soft segments on thermal and mechanical properties of terpoly(ester-ether-ester)s

P. Zdebiak; P. El Fray

Published : 2022-08-24

Vol. 53 No. 10 (2008)

Influence of soft segments on thermal and mechanical properties of terpoly(ester-ether-ester)s

P. Zdebiak P. El Fray

Abstract

The aim of the work was preparation and investigation of new multiblock terpoly(ester-ether-ester)s (TEEE) containing phthalic acid units as in poly(butylene terephthalate) (PBT) (hard segments) and hydrogenated dimer of dilinoleic acid called as dilinoleic acid sequences (DLA) as hydrophobic ester soft segments, and poly(ethylene glycol) (PEG) as hydrophilic ether soft segments. PEG of different molecular weight (1000 and 4600) was used. Synthesis was performed in a presence of a-tocopherol as non-toxic thermal stabilizer since these materials are targeted for biomedical applications. In this paper, the influence of amount and molecular weight of PEG on thermal and mechanical properties of TEEE is discussed.

Keywords

multiblokowe terpolimery ; elastomery termoplastyczne ; poli(glikol etylenowy) ; dimer kwasu linolowego multiblock terpolymers ; thermoplastic elastomers ; poly(ethylene glycol) ; dimer of linoleic acid

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Zdebiak, P., & El Fray, P. (2022). Influence of soft segments on thermal and mechanical properties of terpoly(ester-ether-ester)s. Polimery, 53(10), 764-768. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1367

References

El Fray M.: „Nanostructured elastomeric biomaterials for soft tissue reconstruction”, Warsaw Publishing House of the Warsaw University of Technology, Warsaw 2003.

2. Gogeva T., Fakirov S.: Macromol. Chem.1990, 191, 2355.

3. Szymczyk A., Rosłaniec Z.: Polimery 2006, 51, 627.

4. El Fray M., Slonecki J.: Polym. Plast. Technol. Eng. 1990, 38, 51.

5. El Fray M., Boccaccini A. R.: Mater. Lett. 2005, 59, 2300.

6. „Thermoplastic Elastomers”., (Eds.: Holden G., Legge N. G., Quirk R., Schroeder H. E.), Hanser Publishers, New York 1996.

7. El Fray M.: Eng. Biomater. 2004, 34, 14.

8. Piegat A., El Fray M.: Polimery 2007, 52, 885.

9. El Fray M.: Des. Monomers Polym. 2000, 3, 325.

10. El Fray M.: Macromol. Symp. 1997, 122, 335.

11. Deschamps A. A., Grijpma D. W., Feijen J.: Polymer 2001, 42, 9335.

12. Zdebiak P., El Fray M.: Przem. Chem. 2006, 85, 986.

13. Estes G. M., Cooper S. L., Tobolsky A. V.: J. Macromol. Sci. Rev. Macromol. Chem. 1970, C4, 313.

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P. Zdebiak

P. El Fray mirfray@ps.pl

Affiliation
Szczecin University of Technology, Polymer Institute Division of Biomaterials and Microbiological Technologies, ul. Pułaskiego 10, 70-322 Szczecin