Synteza oraz właściwości termiczne i aplikacyjne anionomerów poli(uretanowo-dimetylosiloksanowych)

Ł. Byczyński; P. Król

Published : 2013-03-30

Vol. 58 No. 3 (2013)

Synthesis, thermal and performance properties of poly(urethane-dimethylsiloxane) anionomers. Part I. Structural studies

Ł. Byczyński P. Król

Abstract

Poly(urethane-dimethylsiloxane) anionomers (PUR-PDMS) were synthesized in two- or three-stage process, with the use of isophorone diisocyanate (IPDI) and poly(oxytetramethylene)diol (PTMG), partially replaced by polydimethylsiloxane diols (PDMS) with different chain structures. 2,2-bis(hydroxymethyl)propionic acid (DMPA) neutralized with triethylamine (TEA) was used as the ionogenic component built into the polyurethane chain and ethylenediamine (EDA) as the extender. The structure of the synthesized polymers was confirmed by FT-IR analysis. By using gel permeation chromatography (GPC) method, the basic differences in molecular weight distribution of the anionomers synthesized with a,w-dihydroxy polydimethylsiloxane and dihydroxysiloxane with both primary -OH groups located at the same end of the chain. From DSC studies it was found that the obtained anionomers show a limited degree of phase separation, which was indicated by the presence of two regions associated with second order phase transitions. They were ascribed to the glass transition temperatures in the range of Tg1 = -27— -30 °C, corresponding to soft segments transitions and Tg2 = 52—72 °C, related to the phase transitions of hard segment domains. A particularly pronounced plasticizing effect was demonstrated by PDMS with two hydroxyl groups at one side of the chain.

Keywords

polisiloksany ; poliuretany ; badania strukturalne ; łańcuch boczny polyurethanes ; polysiloxanes ; anionomers ; pendant chain ; structural studies

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Byczyński, Ł., & Król, P. (2013). Synthesis, thermal and performance properties of poly(urethane-dimethylsiloxane) anionomers. Part I. Structural studies. Polimery, 58(3), 188-194. Retrieved from https://ichp.vot.pl/index.php/p/article/view/724

References

Król P.: Prog. Mater. Sci. 2007, 52, 915.

2. Rościszewski P., Zielecka M.: „Silikony, właściwości i zastosowanie”, WNT, Warszawa 2002.

3. Rahman M. M., Chun H.-H., Park H.: J. Coat. Technol. Res. 2011, 8(3), 389.

4. Pergal M. V., Antic V. V., Govedarica M. N., Godevac D.: J. Appl. Polym. Sci. 2011, 122, 2715.

5. Madhavan K., Gnanasekaran D., Reddy B. S. R.: J. Polym. Res. 2011, 18, 1851.

6. Pergala M. V., Dzunuzović J. V., Kićanović M., Vodnik V.: Russ. J. Phys. Chem. A 2011, 85(13), 2251.

7. Gao C. H., Chen M. Y., Ni J. N., Hua J. J.: Chin. J. Polym. Sci. 2010, 28, 219.

8. Zhou H., Gu T., Yang D., Jiang Z.: Adv. Mater. Res. 2011, 197—198, 1281.

9. Król P., Byczyński Ł.: Przem. Chem. 2007, 86, 643.

10. Chen H., Fan Q., Chen D., Yu X.: J. Appl. Polym. Sci. 2001, 79, 295.

11. Chen R. S., Chang C. J., Chang Y. H.: J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 3482.

12. Byczyński Ł. „Badania nad syntezą wodorozcieńczalnych jonomerów poli(uretanowo-siloksanowych)”, praca doktorska,

Politechnika Rzeszowska, Rzeszów 2010.

13. Stagg H. E.: The Analyst 1966, 71, 557.

14. Jhon Y. K., Cheong I.W., Kim J. H.: Colloids Surf. A2001, 179, 71.

15. Gunatillake P. A., Meijs G. F., McCarthy S. J., Adhikari R.: J. Appl. Polym. Sci. 2000, 76, 2026.

16. Adhikari R., Gunatillake P. A., McCarthy S. J., Meijs G. F.: J. Appl. Polym. Sci. 2000, 78, 1071.

17. Adhikari R., Gunatillake P. A., Brown M.: J. Appl. Polym. Sci. 2003, 90, 1565.

18. Fei G., Shen Y., Wang H., Shen Y.: J. Appl. Polym. Sci. 2006, 102, 5538.

19. Yen M. S., Tsai P. Y.: J. Appl. Polym. Sci. 2003, 90, 233.

Google Scholar

Citing articles via

Statistics

Total abstract views : 47

PDF Downloads : 40