Język Polski
English
Published
: 2022-09-01
Synthesis of macrocyclic and linear oligomers of methyl a-D-mannopyranoside
Abstract
The polycondensation of methyl a-D-mannopyranoside (I) with 1,x-bis(2-formylphenoxy)alkanes (II) using various acid catalysts leads to the formation of macrocyclic compounds [1+1] and [2+2] and linear copolymer. NMR and ESI-MS studies demonstrated the evidence of structure of macrocyclic compounds. The structure of dialdehyde, the nature of the catalyst, and in particular, the molar ratio of catalyst to dialdehyde, show a very pronounced effects on yield of the resulting macrocycles.
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Zasady cytowania
Maślińska-Solich, J., & Kukowka, S. (2022). Synthesis of macrocyclic and linear oligomers of methyl a-D-mannopyranoside. Polimery, 50(9), 651-656. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1672
