Synthesis of macrocyclic and linear oligomers of methyl a-D-mannopyranoside

J. Maślińska-Solich; S. Kukowka

Published : 2022-09-01

Vol. 50 No. 9 (2005)

Synthesis of macrocyclic and linear oligomers of methyl a-D-mannopyranoside

J. Maślińska-Solich S. Kukowka

Abstract

The polycondensation of methyl a-D-mannopyranoside (I) with 1,x-bis(2-formylphenoxy)alkanes (II) using various acid catalysts leads to the formation of macrocyclic compounds [1+1] and [2+2] and linear copolymer. NMR and ESI-MS studies demonstrated the evidence of structure of macrocyclic compounds. The structure of dialdehyde, the nature of the catalyst, and in particular, the molar ratio of catalyst to dialdehyde, show a very pronounced effects on yield of the resulting macrocycles.

Keywords

metylo-a-D-mannopiranozyd ; dialdehyd ; polikondensacja ; katalizator ; poliacetale ; makrocykle ; struktura ; wydajność tworzenia makrocykli polycondensation ; polyacetals ; macrocycles ; methyl a-D-mannopyranoside

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Maślińska-Solich, J., & Kukowka, S. (2022). Synthesis of macrocyclic and linear oligomers of methyl a-D-mannopyranoside. Polimery, 50(9), 651–656. Retrieved from https://ichp.vot.pl/index.php/p/article/view/1672

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J. Maślińska-Solich Jolanta.Maslinska@polsl.pl

Affiliation
Silesian University of Technology, Department of Physical Chemistry and Technology of Polymers, ul. M. Strzody, 44-100 Gliwice, Poland

S. Kukowka

Affiliation
Silesian University of Technology, Department of Physical Chemistry and Technology of Polymers, ul. M. Strzody, 44-100 Gliwice, Poland